C2 - atoms, Ions And Compounds Flashcards
What is the relative charge and relative mass of a proton, neutron and electron?
Proton: charge= 1+ mass=1
neutron: charge= 0 mass=1
electron: charge= 1- mass= 1/1836
what is the charge of an atom and why?
Atoms contain the same number of protons and electrons so the atom is neutral as the charges cancel each other so therefore the overall charge is zero.
what are isotopes?
Atoms of the same element with different numbers of neutrons and different masses.
What are the properties of isotopes of the same element?
- have the same number of electrons
- the chemical properties remain the same as the number of neutrons has no effect on reactions.
- may be small differences in physical properties. (higher mass isotopes have a higher MP and BP and density).
What is an ion and the two types?
A charged atom, the number of electrons and protons are different.
Cations- positive ions, fewer electrons than protons.
Anions- negative ions, more electrons than protons.
What is relative formula mass?
The weighted mean mass of the formula unit of a compound compared to 1/12 th of the mass of a carbon-12 atom.
What is relative isotopic mass?
The mass of an isotope relative to 1/12 th of the mass of a carbon-12 atom
Why is the mass of a carbon-12 atom used as the comparison?
- The mass of a carbon-12 isotope is defined as exactly 12 atomic mass units (12u).
- the standard atomic mass is 1u (mass of 1/12th of a carbon-12 atom
- 1u is approximately equal to the mass of a proton/neutron
What is relative atomic mass (Ar)?
the weighted mean mass of an atom of an element relative to 1/12th of the mass of an atom of Carbon-12.
In Relative atomic mass, what does the weighted mean mass take into account?
- the % abundance of each isotope.
- the relative isotopic mass of each isotope.
What is a mass spectrometer used for?
Used to find % abundances of the isotopes in an element.
How does a mass spectrometer work?
- Sample is placed in the mass spectrometer.
- sample is vaporised and ionised to form positive ions.
- the ions are accelerated:
heavier ions= slow & harder to deflect
lighter ions= faster & easier to deflect. - the ions are detected on a mass spectrum as a mass to charge ration(m/z). Each ion adds to the signal, so the greater the abundance, the larger the signal.
How do you calculate the mass-to-charge ratio (m/z)?
m/z = relative mass of ion/ relative charge of ion
What are the 4 sections in a mass spectrometer?
- ionisation area
- acceleration area
- flight path
- ion detector
How do you calculate relative atomic mass?
Ar = (M1 x A1) + (M2 x A2) + … / 100
A=abundance
M=mass