C2 Flashcards

1
Q

How are elements ordered in the periodic table?

A

In order of their atomic weights

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2
Q

How are elements arranged in groups and periods in the periodic table?

A

Elements with similar properties were put in the same group and they are ordered in order of their atomic weights

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3
Q

Why was the periodic table a breakthrough in how to order elements?

A

Because before this there was no correct way of ordering elements and no way to properly understand chemical elements.

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4
Q

What is a group in the periodic table?

A

Vertical columns which contain elements with similar properties.

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5
Q

What is a period in the periodic table?

A

The horizontal rows in a periodic table.

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6
Q

How does electronic structure in group 1,2 and 3 link to the periodic table?

A

Because group 1,2 and 3 on the periodic table have to lose electrons to attain the electronic structure of the noble gases.

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7
Q

Are noble gases reactive or unreactive?

A

Unreactive

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8
Q

Compare the electronic structure of a metal and non metal

A

Metals conduct electricity but non metals are usually electrical insulators. Exceptions are some forms of carbon. In general, metals also have much higher melting and boiling. Metals are ductile and malleable, whereas non metals solids are brittle.

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9
Q

Why are noble gases unreactive?

A

They are monatomic (single-atom) gases. So they have no tendancy to react and modify their electronic structures by forming molecules.

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10
Q

Explain the noble gases trends in their boiling points

A

The boiling points get higher going down group 0. Helium at the top boils at -269°C whereas radon,at the bottom boils at -62°C.

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11
Q

Name the first three elements in group 1

A

Lithium (Li), sodium (Na) and potassium (k)

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12
Q

Do they group 1 metals have low or high densities?

A

Low densities

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13
Q

Write a word equation of how a group 1 metal reacts with water

A

Sodium + water – sodium hydroxide + hydrogen

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14
Q

Explain why the first three group 1 elements float on water

A

The water reacts with the metal to form hydrogen gas. Potassium reacts so vigorously with water that the hydrogen produced ignites. It burns with a lilac flame, coloured by the potassium ions formed in the reaction.

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15
Q

How can you show that hydrogens and metal hydroxides are made when group 1 metals react with water?

A

They are called alkali metals because they also produce a metal hydroxide when reacting with water. The hydroxides of alkali metals are all soluble in water. This solution is colourless with a high pH.

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16
Q

What safety precautions have to be taken when dealing with group 1 metals?

A

They are to be stored in oil which stops them reacting with oxygen in the air.

17
Q

How do group 1 metals form ions with a +1 charge when they react with non-metals? (Optional question, very long answer, will probably help in the exam though)

A

They react vigorously with non-metals such as chlorine gas, which produce metal chlorides, which are white solids. The metal chlorides all dissolve readily in water to from colourless solutions. Reactions get more vigorous as you go down the group. Because it becomes easier to lose the single electrons in the outer shell to form ions with a +1 charge. They react in a similar way with fluorine, bromine and iodine. The solutions formed are all colourless.

18
Q

Name the first 4 elements in group 7

A

Fluorine, chlorine, bromine and iodine

19
Q

Describe the main properties of halogens

A

They have low melting points and boiling points. Their melting and boiling points increase going down the group.

They are poor conductors of heat and electricity.

20
Q

Explain why elements in group 7 react similarly

A

Because they all have 7 electrons in their outermost shell and their electronic structure determines the way they react with other elements.

21
Q

What is the trend in reactivity in group 1?

A

Get more reactive going down the group

22
Q

What is the trend in reactivity in group 7?

A

The elements get less reactive going down the group

23
Q

How does electronic structure affect the trend of group 1 elements?

A

Because the atoms get larger so the single electron in the outermost shell (highest energy level) is attracted less strongly to the positive nucleus. The electrostatic attraction with the nucleus gets weaker because the distance between the outer electron and the nucleus increases.

24
Q

How does the electronic structure affect the trend in reactivity in group 7?

A

When group 7 elements react their atoms gain an electron in their outermost shell. Going down the group the outermost shell’s electrons get further away from the attractive force of the nucleus, so it is harder to attract and gain an extra incoming electron.

25
Q

What does the group number of the periodic table tell you about an element?

A

The group number in the periodic table tells you the number of electrons in the outermost shell of an atom.

26
Q

What model for ordering elements was made in 1808?

A

In 1808 John Dalton arranged the elements in order of their atomic weight.

27
Q

What significant model was made in 1864 for ordering elements?

A

John Newlands made a ‘law of octaves’ table.

28
Q

What was the problem with John Newlands ‘law of octaves’ table?

A

He assumed all elements had been found. Didn’t take into account that chemists were still forming new ones. So he filled in his octaves even though some of the elements were not similar at all.

29
Q

What elements did John Newlands ‘law of octaves’ table work up to?

A

Calcium

30
Q

What happened in 1869 with ordering elements?

A

Russian chemist, Dmitri Mendeleev cracked the problem, when around 50 elements had been discovered.

31
Q

What did Mendeleev do with the elements?

A

He arranged them in a table. He placed them in the order of their atomic weights.

32
Q

What was Mendeleev’s last step?

A

He arranged the elements so that a periodic pattern in their properties could be seen.

33
Q

What was the only problem with Mendeleev’s breakthrough?

A

Not all elements fell in with his pattern, for example argon. It was a mystery for decades.

34
Q

When did scientists start to learn more about the structure of an atom?

A

Not until the start of the 20th century.

35
Q

How does electronic structure in group 5,6 and 7 link to the periodic table?

A

Group 5,6 and 7 gain electrons to form negative ions to attain the electronic structure of noble gases.