C1: Acids, Bases and Salts Flashcards
what is an acid?
a substance containing hydrogen that can be replaced by a metal to for a salt
What is an acid salt?
A salt that is formed when the H+ ions in an acid are only partially replaced by metal or ammonium ions
An acid salt id formed when only some of the H+ ions in an acid are replaced a metal ion or ____________
NH4+ Ions
A ___________ salt is formed when all the hydrogen ions in an acid are replaced by _________ or _________
Normal salt
metal ion
Ammonium ion
which of the following salts is an acid salt?
- H2SO4
- KOH
- KHSO4
- CaCO3
- NaH2PO4
KHSO4
NaH2PO4
What is the Basicity of an acid?
The number of protons produced per molecule of acid when dissolved in water
what are the main chemical reactions of acids in aqueous solution?
- acids react with reactive metals to form a salt and hydrogen
- acids react with bases to form salt and water
- acids react with metal carbonates and hydrogencarbonates to form a salt, water and CO2
Acids except ________ react with metals above hydrogen in the reactivity series to produce salt and hydrogen
HNO3
When HNO3 reacts with a reactive metal the products are:
Salt + Oxides of nitrogen
which of these acids will form both normal salts and acid salts?
HNO3
H2SO4
H3PO4
HCl
H2SO4
H3PO4
which compounds is the plumbate ion derived from?
PbO and Pb(OH)2
What are acid anhydrides
compound that reacts with water to form an acid
name 4 examples of acid anydrides
- carbon dioxide
- sulphur dioxide
- sulphur trioxide
- nitrogen dioxide
what is a base?
a proton acceptor
when bases react with acids the _________ or ________ ions from the base accept the protons from the __________ to form water
Oxide(O2-)
OH-
Acid
what is an alkali
a soluble base that dissolves in water to form a solution that contains OH- ions
most bases are ________ and as a result most are not __________
insoluble
alkalis
what are the chemical reactions of bases
- react with acids to form salt and water
- react with ammoniums salts to form salt, water and ammonia
Mg(OH)2 (s) + 2NH4Cl (s) gives ________
MgCl2(s) + 2H20(l) + 2HN3(g)
CaO(s) + (NH4)2SO4 ——->
CaSO4(s) + H20(l) + NH3(g)
Name 4 indicators
- litmus
- phenolpthalein
- methyl orange
- screened methyl orange
a ____________ is fully ionised when dissolved in water to produce H+ ions.
strong acid
a ____________ is fully ionised when dissolved in water to produce OH- ions.
strong base
example of a base that is partially ionized when dissolved in water
NH3
definition of a weak base
partially ionises when dissolved in water
which of these substances will have a high concentration of ions when dissolved in water:
HCl
CH3COOH
NaOH
NH3
H2SO4
HCl
H2SO4
NaOH
these react with both acids and strong alkalis to form salt and water
amphoteric oxides or hydroxides
which of the following metals will form amphoteric bases?
Zn
Ca
Ba
Pb
Hg
Al
Cu
Ag
Zn
Pb
Al
when Zn(OH)2 reacts with a strong base what anion is present in the resulting salt?
an example is :
Zincate - ZnO22-
2NaOH + Zn(OH)2 —–> Na2ZnO2 + 2H2O
when Pb(OH)2 reacts with a stong base what anion is present in the resulting salt?
an example is:
Plumbate ion - PbO22-
2KOH + Pb(OH)2 —–> K2PbO2 + 2H2O
when Al(OH)3 reacts with a stong base, what anion is present in the resulting salt?
An example is _________
Aluminate ion - AlO2-
2NaOH + 2Al(OH)3 ——> 2NaAlO2 + 4H2O
the 4 main groups of oxides are:
- acidic oxides
- basic oxides
- amphoteric oxides
- neutral oxides
acidic oxides react with (1)_________ to form salt and water. They also react with (2)__________ to form acids and therefore are called (3)___________. They are oxides of (4)_____________.
- alkalis
- water
- acid anhydrides
- non-metals
Na2O is an example of a (1) ____________ but is also a (2)_____________. It reacts with
(3)__________ to form salt an water.
- basic oxide
- alkali
- acids
basic oxides are oxides of _________
metals
Neutral oxides are oxides of some (1)____________ which do not react with (2)_____________ or (3)_________. examples of neutral oxides are(4)_______________
- non-metals
- acids
- alkalis
- CO, NO, N2O
definition of a salt
substance formed when some or all of the H+ ions in an acid have been replaced by metal or ammonium ions
from which base is the zincate ion derived?
ZnO and Zn(OH)2
from which base is the aluminate ion derived?
Al2O3 amd Al(OH)3
a salt is substance formed when some or all of the (1)_______ ions in an (2)_________ have been replaced by metal or (3)_________ions
- H+
- acid
- NH4-
the main methods of preparing salts are:
reaction with acids
direct combination
precipitation reactions
when preparing a soluble salt these two general methods are used:
- reaction with acids
- direct combination
when acids are used to prepare salts these are the possible reactions:
acid + alkali - titration
acid + reactive metal
acid + insoluble base
acid + insoluble carbonate
an insoluble salt is produced by :
ionic precipitation
_____________ is the method of preparing salts of Na, K, or NH4-
titration
when producing an anhydrous soluble chloride this method is used
direct combination
salt preparation by direct combination is a reaction between (1)___________ and a (2) ____________
- chlorine gas
- reactive metal
This salt is a component of baking soda and is used to make cakes
NaHCO3
what is the formula for baking soda and what kind of salt is it?
NaHCO3
it is an acid salt
these salts are used as a preservative
sodium benzoate
NaCl
NaNO2
NaNO3
NaCl is used for
flavouring and food preservative
used to preserve meats such as bacon and ham by destroying bacteria. Also adds flavour and colour. Often used with NaCl
Sodium nitrite and sodium nitrate
a use of CaCO3 is:
to manufacture cement
another name for CaCO3
limestone
Uses of Calcium sulphate
to manufacture plaster of Paris used a building material. Also for setting broken ones
another name for calcium sulphate
gypsum
Magnesium sulphate is also known as (1)____________ and is used in (2)_______________, where it is used to relieve pain, inflammation. also used as laxative. Also used in (3)____________ where it improves plant growth
- epsom salt
- medicine
- agriculture
this salt can lead to hypertension if consumed in excess
NaCl
this salt may increase the risk of cancer and increase asthma in children
Sodium Benzoate
Formula for sodium benzoate
C6H5COONa
dangers of sodium nitrite and sodium nitrate
- increased risk of cancer
- may cause brain damage in infants
what is a neutralization reaction?
reaction between acid and base to form salt and water
The (1)_________ or (2) _____________ of a neutralization reaction is when all of the OH- and H+ ions have been used up
- neutralization point
- end point
The neutralization point or end point of a neutralization reaction is when all of the (1) ___________ and (2)___________ ions have been used up and the final solution has a pH of (3)___________
- OH-
- H+
- 7
2 ways of determining the end point of a neutralization reaction
- using an indicator
- using temperature change
key point to remember when determining the concentration of an aqueous alkali solution:
react it with a known amount of standard aqueous acid solution
key point to remember when determining the concentration of an aqueous acid solution:
react it with a known amount of standard alkali solution
how to use titration to calculate the concentration of an alkali (steps)
- obtain a known volume of standard acid solution and place it in a conical flask
- determin the volume of alkali needed to neutralize the acid
- calculate the number of moles of acid in the standard acid solution
- balance the acid- base equation to determin the mole ratio of the acid and alkali
- use the mole ratio to determine the number of moles of the alkali that was neutralised
- now use the volume and number of moles of alkali used in the titration to work out its molar concentration.
definition of molar concentration
number of moles in 1dm3 of a solution
1dm3 is the same as (1)_____________ or (2)_____________
- 1000cm3
- 1L
water of chrystalization is defined as __________
a fixed proportion of water molecules held in the crystal lattice of a salt