C02 absorption Flashcards
C02 absorber
- chemically neutralizes C02
- C02 + H20 = carbonic acid
- Base neutralizes acid
- end product = carbonate H20 & heat
4 types of absorbers
- Soda Lime
- Calcium hydroxide lime (amsorb plus)
- Litholyme (lithium hydroxide)
- Baralyme
Soda Lime components sodium hydroxide (NaOH) lime
4% NaOH sodium hydroxide
1% KOH potassium hydroxide
80% CaOH calcium hydroxide
15% water
0.2% silica
Soda Lime equation
C02 + H20 = H2C03
H2C03 + 2Na0H (K0H) = Na2C03 (K2C03 + 2H20 + HEAT
Na2C03 (K2C03) + Ca0H = CaC03 + 2Na0H (K0H) + HEAT
*quicker Rex
OR
C02 + Ca0H2 =CaC03 + H20 + HEAT
*slower rxn
C02 combines with H20 to form carbonic acid which reacts with. hydroxides to form Na or K carbonate heat and H20
Soda Lime absorption
26L of C02/ 100g of absorbent granules
1lb of CaOH absorbs 0.59lb of C02
Calcium Hydroxide Lime
Amsorb plus components
80% CaOH
1-4% calcium chloride CaCl
16% water
calcium sulfate and poly-vinyl-pyrrolidine
Calcium Hydroxide (CaOH)Lime rxn
C02 +H20 = H2C03
H2C03 + Ca0H2 = CaC03 +2H20 + HEAT
CaOH absorption
absorbs 10L/ 100g of absorbent granules
1lb of CaOH absorbs 0.59lb of C02
Lithium Hydroxide (Li0H) Litholyme components
75% lithium hydroxide (Li0H)
<3% lithium chloride (LiCl)
12-19% H20
Litholyme rxn
2Li0H x H20 + C02 = Li2C02 + 3H20 - HEAT
Litholyme absorption
almost 1:1 ratio
1lb of Li0H absorbs 0.91lb of C02
Baralyme components
20% Ba0H
80% Ca0H
small amounts of Na0H and K0h
*no water or hardening agent
Baralyme rxn
Ba0H + 2(8H20) + C02 = BaC03 + 9H20 + HEAT
9H20 + 9C02= 9H2C03
9H2C03 + 9Ca(0H) = 9CaC03 + 18H20 + HEAT
Baralyme risks
- more likely to dry out ( risk of C0)
- risk of fire
- contain some Na0H and K0H (risk of compound A)
Baralyme absorption
26L/ 100g of absorbent granules
*same as soda lime but slightly less efficient