Buffers and indicators Flashcards
Define buffer
solution which resist changes of acidity and alkanity when small quantities of acid and alkali is added
Whats the equation for buffers?
HA –> H+ + A-
Describe adding small amount of acid
Add H+ increasing H+ conc
H+ react with A-
Eqm shifts to left to reduce H+ ions
Describe adding small amount of alkali
Add OH- increasing OH- conc
React with H+ to produce H2O
Eqm shifts to right to replace H+ that have reacted
How do you work out pH of buffers if its acids and their salts?
Conc of HA and A-
Ka expression to get H+
pH
What are the indicators used?
SA and SB - Phenolphthalein
SA and WB - Methyl red
WA and SB - Phenolphthalein
Describe colour change of indicators?
Increase in H+ shifts to left - Red
Increase in In- shifts to right - blue
Define equivalence point
When sufficient acid has been added to neutralise
volume when moles are equal
Define end point
volume of acid and alkali added when colour changes