Born haber cycle Flashcards

1
Q

what is the born haber cycle?

A

a special type of hess cycle that represents the formation of an ionic compound

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2
Q

endo

A

arrow is up

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3
Q

exo

A

arrow is down

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4
Q

What are the 5 features of a born haber cycle

A
  1. enthalpy of formation AHF
  2. atomisation of the non metal and metal AHat - TURN INTO GASEOUS ATOMS
  3. ionization of the metal AHi Na+ + Cl- + e-
  4. Electron affinity of the non metal AHea (negative ion) Na+ and Cl-
  5. Lattice enthalpy of formation AHI
    NaCl
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5
Q

What two factors affect lattice formation enthalpy

A
  1. charge

2. size

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6
Q

what is the perfect ionic model of a lattice - theoretical

A

it assumes that all the ions are spherical and has a even distribution of electron

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7
Q

Experimental enthalpy

A

shows that ionic compounds have some covalent character

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8
Q

why aren’t positive and negative ions always spherical

A

Positive ions polarize neighbouring negative ions to different extents – Partial covalent bonding =the electrons in the negative ion are pulled towards the positive ion.

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9
Q

if the experimental and theoretical enthalpies are different….

A

the compound has a lot of covalent characters

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10
Q

if the experimental and theoretical enthalpies are similar

A

the compound has very little of covalent characters

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