Born haber cycle Flashcards
what is the born haber cycle?
a special type of hess cycle that represents the formation of an ionic compound
endo
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exo
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What are the 5 features of a born haber cycle
- enthalpy of formation AHF
- atomisation of the non metal and metal AHat - TURN INTO GASEOUS ATOMS
- ionization of the metal AHi Na+ + Cl- + e-
- Electron affinity of the non metal AHea (negative ion) Na+ and Cl-
- Lattice enthalpy of formation AHI
NaCl
What two factors affect lattice formation enthalpy
- charge
2. size
what is the perfect ionic model of a lattice - theoretical
it assumes that all the ions are spherical and has a even distribution of electron
Experimental enthalpy
shows that ionic compounds have some covalent character
why aren’t positive and negative ions always spherical
Positive ions polarize neighbouring negative ions to different extents – Partial covalent bonding =the electrons in the negative ion are pulled towards the positive ion.
if the experimental and theoretical enthalpies are different….
the compound has a lot of covalent characters
if the experimental and theoretical enthalpies are similar
the compound has very little of covalent characters