Book: Ch. 2 Flashcards
Define an element.
An element is the simplest type of matter with unique physical and chemical properties. It consists of only one kind of atom and, therefore, cannot be broken down into a simpler type of matter by any physical or chemical methods.
Several elements occur in molecular form (which means…): _____
a molecule is an independent structure of two or more atoms bound together (Figure 2.1B). Oxygen, for example, occurs in air as diatomic (two-atom) molecules.
Define a compound.
A compound consists of two or more different elements that are bonded chemically (Figure 2.1C). That is, the elements in a compound are not just mixed together: their atoms have joined in a chemical reaction. Many compounds, such as ammonia, water, and carbon dioxide, consist of molecules. But many others, like sodium sulfate (which we’ll discuss shortly) and silicon dioxide, do not.
What are the two defining features of compounds?
- The elements are present in fixed parts by mass (fixed mass ratio). This is so because each unit of the compound consists of a fixed number of atoms of each element.
- A compound’s properties are different from the properties of its elements. Table 2.1 shows a striking example: soft, silvery sodium metal and yellow-green, poisonous chlorine gas are very different from the compound they form—white, crystalline sodium chloride, or common table salt!
Define a mixture.
A mixture consists of two or more substances (elements and/or compounds) that are physically intermingled, not chemically combined.
the law of mass conservation says _____
the total mass of substances does not change during a chemical reaction. The number of substances may change and, by definition, their properties must, but the total amount of matter remains constant.
law of definite (or constant) composition says _____
no matter what its source, a particular compound is composed of the same elements in the same parts (fractions) by mass
The fraction by mass (mass fraction) is _____
the part of the compound’s mass that each element contributes.
The percent by mass (mass percent, mass %) is
he fraction by mass expressed as a percentage (multiplied by 100): Mass percent = mass fraction x 100
Mass of element = _____
mass of compound x mass fraction
The law of multiple proportions says _____
If elements A and B react to form two compounds, the different masses of B that combine with a fixed mass of A can be expressed as a ratio of small whole numbers. . .The law of multiple proportions tells us that in two compounds of the same elements, the mass fraction of one element relative to the other element changes in increments based on ratios of small whole numbers.
Dalton expressed his theory in a series of postulates, presented here in modern terms: _____
- All matter consists of atoms, tiny indivisible units of an element that cannot be created or destroyed.
- Atoms of one element cannot be converted into atoms of another element. In chemical reactions, the atoms of the original substances recombine to form different substances.
- Atoms of an element are identical in mass and other properties and are different from atoms of any other element.
- Compounds result from the chemical combination of a specific ratio of atoms of different elements.
Dalton’s postulates explain the mass laws: _____
- Mass conservation. Atoms cannot be created or destroyed (postulate 1) or converted into other types of atoms (postulate 2). Therefore, a chemical reaction cannot pos- sibly result in a mass change because atoms are just combined differently.
- Definite composition. A compound is a combination of a specific ratio of different atoms (postulate 4), each of which has a particular mass (postulate 3). Thus, each element in a compound must constitute a fixed fraction of the total mass.
- Multiple proportions. Atoms of an element have the same mass (postulate 3) and are indivisible (postulate 1). The masses of element B that combine with a fixed mass of element A must give a small, whole-number ratio because different numbers of B atoms combine with each A atom in different compounds.
Explain cathode rays?
To discover the nature of an electric current, some investigators tried passing it through nearly evacuated glass tubes fitted with metal electrodes. When the electric power source was turned on, a “ray” could be seen striking the phosphor-coated end of the tube, which emitted a glowing spot of light.
The main conclusion of experiments with cathode rays was _____
that cathode rays consist of negatively charged particles found in all matter. The rays become visible as their particles collide with the few remaining gas molecules in the evacuated tube. Cathode ray particles were later named electrons.
The main conclusion of experiments surrounding electrons was that its mass was (relatively) _____
extremely small
Who discovered the atomic nucleus and how?
- Ernest Rutherford
- Shot alpha particles at gold foil, for them to be deflected by the foil; the rare deflects led Rutherford to conclude that the “plum-pudding” model, instead concluding that all positive charge and mass of the atom was contained in a tiny region in the atom called the nucleus.
An atom is _____
an electrically neutral, spherical entity composed of a positively charged central nucleus surrounded by one or more negatively charged electrons (Figure 2.7).
An atom is neutral because _____
the number of protons in the nucleus equals the number of electrons surrounding the nucleus.
An atomic nucleus consists of _____
The proton (p^+) has a positive charge, and the neutron (n^0) has no charge; thus, the positive charge of the nucleus results from its protons.
The atomic number (Z) of an element equals _____
the number of protons in the nucleus of each of its atoms. All atoms of an element have the same atomic number, and the atomic number of each element is different from that of any other element.
The mass number (A) is _____
the total number of protons and neutrons in the nucleus of an atom.
The atomic symbol (or element symbol) of an element is _____
based on its English, Latin, or Greek name, such as C for carbon, S for sulfur, and Na for sodium (Latin natrium).
Isotopes of an element are atoms that _____
have different numbers of neutrons and therefore different mass numbers. Most elements occur in nature in a particular iso- topic composition, which specifies the proportional abundance of each of its isotopes.
All isotopes of an element have _____ chemical behavior
nearly identical
The atomic mass unit (amu) is _____
1/12 the mass of a carbon-12 atom. The mass of an atom is measured relative to the mass of an atomic standard. The modern standard is the carbon-12 atom, whose mass is defined as exactly 12 atomic mass units.