Book 1 Flashcards
Substances that sublime
Iodine
Ammonium chloride
Iron(iii) chloride
Sulphur
Benzoic
Fractional distillation
Fractional distillation
Simple distillation cannot be used to separate a mixture of two or more miscible liquids. Fractional distillation is used to separate a mixture of two or more miscible liquid with relatively close boiling point into its component fractions.
A fractionating column is introduced between the distilating flask and the condenser. This is where the actual separation occurs. Vapours with higher boiling points would condense as they enter the upper portion. The fractional distillation process is repeated until all the components fractions in the mixture are distilled over.
This method is used to separate crude oil or petroleum into its component fractions such as natural gas, petrol, kerosene, gas oil, heavy oil and bitumen. It is also used obtain pure nitrogen from air.
In crystallization, the salt solution is first heated to evaporate some of the solvent. The solution becomes saturated. When the saturated solution is cooled, crystals of the solute begin to form. Examples of such salts are:
CuSO4.5H20,
Cu(No3)2.3H20,
FeS04.7H20,
Zn(NO;)2.6H20, MgS04.7H20 etc.
Distillation
Used to recover a solvent from a solution
Different boiling point
Density
Mass/volume
Factors that affect density determination
Temperature
Air bubbles
Air pressure
Viscosity
Specific gravity
PURE AND IMPURE SUBSTANCES
Impurities lower the melting point of a substance and raises the boiling point. The melting and boiling point of a given pure substance is fixed at a particular temperature.
Commonest absorbent medium for chtomatography
Filter paper
Simple distillation
Large difference in boiling point
Bioling point of water
Boiling point determination is used to ascertain the purity of water. Pure water boils at 100°C.
The use of CuSO, and COCl, are used to determine the presence of water. Water changes the colour of CuSO4 from white to blue. If COCl is used the colour changes from blue to pink.
Rubber latex and vulcanizer solution are
Mixtures
Sand bath
Used to bring about steady rate in evaporation