Bonding test feedback Flashcards
What is meant by the term covalent bond?
The nuclear attraction between the nucleus of multiple atoms and the shared pair of electrons.
What is meant by the term ionic bond?
The electrostatic forces of attraction between positively and negatively charged ions in a giant lattice.
What is a permanent dipole and how is it formed?
Formed when two atoms in a covalent bond have a difference in electronegativity, causing electrons to be pulled closer to the more electronegative atom (an unequal sharing of electrons). This creates a partial negative charge on one atom and a partial positive charge on the other, resulting in a polar bond.
Explain why a molecule of Hydrogen chloride is polar.
Because chlorine is more electronegative than hydrogen. This causes the shared electrons in the covalent bond to be pulled closer to the chlorine atom, giving it a partial negative charge and leaving the hydrogen atom with a partial positive charge.
In terms of electron pairs, explain why the bond angles in NH4+ are all 109.5º
- 4 total electron pairs
- 4 bonding pairs
- 0 lone pairs
- so bond angles are all 109.5º
- as the electron pairs are arranged as far apart from each other as possible.
Explain why the shape of NH3 is not the same as the shape of BF3
As NF3 has
- 4 total electron pairs
- 1 lone pair
- 3 bonding pairs
so is trigonal pyramid and 107º
whereas,
BF3 has
- 3 bonding pairs
- 3 total electron pairs
- 0 lone pairs
so is trigonal planar and 120º
Explain why shape X has no overall polarity.
- dipoles cancel each other out
- arranged symmetrically around central atom
- so overall non-polar
Explain why X has a greater b.p. than Y.
mention:
- number of electrons
- van der Waals
- other intermolecular forces e.g. hydrogen
- so more heat energy required to overcome.