bonding and structure (2) Flashcards

1
Q

one way in which diamond differs from graphene and graphite

A

poor electrical conductivity

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2
Q

what is the trend in boiling temperatures of hydrogen halides

A

hydrogen chloride-> hydrogen iodide increases as size of halogen atoms increases (more electrons) which increases the strength of the London forces
hydrogen fluoride has a permanent dipole

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3
Q

what happens when ammonia gas reacts with hydrogen chloride gas

A

acid base

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4
Q

what is a metallic bond

A

electrostatic force of attraction between positive metal ions and delocalised sea of electrons

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5
Q

what is an ionic bond

A

electrostatic force of attraction between oppositely charged ions

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6
Q

what is a covalent bond

A

electrostatic attraction between two nuclei and the shared pair of electrons

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7
Q

which has higher melting temperatures, group 1 or 2

A

group 2:
-higher charge so electrostatic forces harder to overcome as electrons more attracted to nucleus
-smaller ionic radius due to added electron increasing attraction to nucleus, harder to overcome forces

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8
Q

which has higher melting temperatures, period 1 or 2

A

period 1: smaller ionic radius

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9
Q

what do metals and acid make

A

hydrogen gas and salt

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10
Q

what do metals and water make

A

metal hydroxide and hydrogen gas

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11
Q

why do ionic compounds have high melting temperatures

A

because each ion is surrounded by multiple other ions so there are a large number of forces to be overcome, ionic bonds require more energy to break

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12
Q

why do ionic compounds conduct in solution/when molten

A

when solid there are no free ions so unable to carry charge
when dissolved in solution ions are free to move and carry charge

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13
Q

properties of ionic compounds

A

-hard solids
-soluble in water
-brittle

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14
Q

what is ionic bond strength affected by

A

1) higher charge on cation/anion = stronger forces
2) closer packed ions = stronger forces
3) geometry

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15
Q

evidence that ions exist

A

electrolysis, migration of ions
physical properties: high melting temp + solubility in water required

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16
Q

what are valence electrons

A

electrons in the outer shell of an atom/ion

17
Q

what is a lone pair

A

pair of electrons not used in bonding

18
Q

what is a dative covalent bond

A

a covalent bond with both electrons in the shared pair provided by one atom

19
Q

how does bond length affect bond strength

A

shorter bonds are stronger as the atoms are held closer together so forces of attraction are greater, requiring more energy to overcome