Bonding and nanoparticles and states of matter Flashcards
What are the three types of bonding?
Ionic bonding
Covalent bonding
Metallic bonding
Covalent bonding between…
Two non-metals
Ionic bonding between…
A metal and non-metal
Metallic bonding…
Electrostatic force of attraction within a metal
Ions
When an element loses or gains an electron
An ionic compound is a…
giant structure
Ionic bonding: High or low melting and boiling point? Why?
High because the giant structure
really strong bonds
need a lot of energy to break
Ions are very…
closely packed together
Do ions conduct electricity?
Yes, when they are in the water or are molten
Why ions conduct electricity when in water or molten
Then they can carry a charge because they are free to move
Metals always… an electron and a non-metal
always… an electron
lose
gains
… … between ions
Strong electrostatic forces
What should we consider before writing a ratio of an ionic bond?
The metal goes first
It is supposed to be in its simplest form
What are the limitations in showing ions in 3D?
Each of the ions are represented as spheres
Does not show the charges
How the ions were formed
What are the limitations in showing ions in 2D?
The diagram is not three dimensional
Does not show the structural arrangement of ions
What are the limitations in showing ions in ball and stick
No sticks/gap between the bonds
Does not show charges
Difference between an ion and an atom?
Atom when neutral
Ion when there is a charge
After the covalent bond has been formed all elements must have…
a full outer shell
Covalent bonding can also be in an element
Because gases are diatomic molecules except for the noble gases
How many pairs can you have in a covalent bond
Up to 3
In a covalent bond can there be one electron more contributed than the other elemen?
No, it should be in pairs
Limitations of covalent bonding in Dot and cross diagrams?
Size of the atom
Intermolecular forces
Limitations of covalent bonding in a structure
How covalent bonds are formed
Size of the atom
Limitations of covalent bonding in ball and stick method?
How covalent bonds are made
That bonds are not sticks
Limitations of covalent bonding in space-filling model
How covalent bonds are formed
Which elements are present( unless given a color key)
Limitations of covalent bonding in 2D
Not accurate
Limitations of covalent bonding in 3D
Difficult to see 3D packing with no spacing
Intermolecular forces are…
weak and are easy to break
Small molecules conduct/ does not conduct electrecity?
does not
Intermolecular forces strength increases as…
the bigger the molecule
Polymers and fullerenes are…
large molecules
covalent bonding
Name covalent bonding- giant molecules
Silicon dioxide
diamonds
graphite
graphene
Polymers and fullerenes have a … intermolecular force
strong
Giant molecules covalent bond have … intermolecular forces
no
Giant molecules properties
Does not conduct electrecity
Usually insoluble in water
no intermolecular forces
Allastropes
Different forms of same element
Allastropes of carbon
Diamond
Graphite
Graphene
Fullerenes
Properties of diamond
Allastrope of carbon Carbon in group 4 so can form a maximum of 4 bonds Hardest natural material Has a very high melting point it does not conduct electricity
Properties of Graphite
Each carbon atom forms 3 covalent bonds
This forms a layer of hexagonal rings
Layers are free to move over each other as there are no covalent bonds between layers
Has high boiling and melting point
It does conduct electricity and thermal energy because there is a delocalize electron free to carry a charge
There is weak forces between layers
Properties of graphine
one layer of graphite
one atom thick- one layer so if you see it sideway then it is one layer of carbon joined together so thickness of one carbon
Properties of fullerenes
A molecule of carbon atoms forming a hallow 3D shapes
Based on hexagonal rings of carbon atoms
Rings may contain 5 to 7 carbon atoms
First discovered was fullerene Buckminster, fullerene
Can be used for drug delivery, a lubricant and a catalyst
Drug delevery- hexagonal ring can be used as a cage and put in a certain part
Lubricant
Something that makes something slippery
Why are fullerenes used to make tennis rackets?
Hard impact does not break will stretch
Properties of fullernes- nanotubes
Nanotubes are cyndrical fullerenes High tensile strength High electrical conductivity High thermal conductivity Used for reinforcing materials e.g tennis racket and bullet vests if you stretch it it does not break
In metallic bonding can you conduct electrecity
Yes because in atom there is a delocalised electron so it can carry charge
Metallic bonding malleable?
yes, atoms can slide over each other
Alloys
Mixture of metals
What hapeens within a alloy
metal becomes stronger and it is difficult for layers to slide over each other because the layers are broken cause atoms are of different sizes
States of matter- limitations of a particle model
Assumes that paticles are the same in reality from different elements
mass or size
the force of attraction between them
energy
Melting point
point of temp when it turns from solid to liquid
When you heat a solid the particle svibrate and the force of attraction weakens
Boiling point
Is when it turns from a liquid to a gas
they vibrate a lot and then the force of attractio breaks
Melting and boiling point depends on:
The type of bonding and structure
covalent structure
the length of the chain( more links) and forces between particles
What are the state symbols for: liquid solid gas aqueous
l
s
g
aq
When aqueous?
When something is dissolved in water
Most acid and alkali solutions are aqueous
All acids have hydrogen
Alkalis will end in OH or O
Every liquid is aqueous unless it is a pure form like pure water
An ionic bond will be a aqueous
Size of a nanometer
1 billion times smaller than a meter
Are smaller than fine particles( PM (2.5 lowercase))
Smaller than coarse particles( PM (10 in lower case))
Because nanoparticles are so small they have a
very high surface area to volume ratio( useful in chemical reactions)
Uses of nanoparticles: ( at least 4)
Cosmetics clothing healthcare industrial biomedical food catalyst paint
Why are people concerned about nm?
Because they say they can be toxic and can enter the bloodstream and brain.
Before increasing the number of us they should do more research