Bonding Flashcards

1
Q

What are the properties of a dental adhesive?

A
  • provide a high bond strength in dental tissues
  • easy to use
  • safe to use
  • durable and impermeable bond.
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2
Q

How does the acid etch bond to enamel?

A

-long enamel prisms are imperfectly filled with hydroxyapatite crystals and when cid is applied the surface is roughened to produced a characteristic etch pattern.
-This roughened surface allows interlocking of materials (mechanical) of resin filling materials
The etching also increases the surface energy of the enamel surface by removing surface contaminants leading to better wettability of the enamel.
Better wettability allows the resin to adapt better to roughened enamel surface.
For this to work the enamel must be dry. Moisture contamination will prevent flow of the resin into the etched surface.
Enamel bonding is essentially Mechanical

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3
Q

What acid is most commonly present in acid etch and what strength is it?

A

-Phosphoric acid, 30-50%.

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4
Q

What happens when a lo viscosity Bis-GMA resin is applied to the etched dried enamel surface?

A

penetrate into the rough surface and light cured.

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5
Q

What is the composition of dentine?

A
  • 20% organic (collagen)
  • 70% inorganic (mostly hydroxyapatite)
  • 10% water
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6
Q

What makes dentine a wet surface?

A

-The fluid from the pulp flows up to the dentine floor of any cavity.

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7
Q

Where in the dentine has more tubules?

A

The dentine near the pulp has more tubules and increased moisture content. LOW SURFACE ENERGY.

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8
Q

Why do most simple bonding agents not adhere to dentine?

A

Dentine is hydrophilic whereas most simple bonding agents are hydrophobic.

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9
Q

What is the smear layer of dentine?

A

The smear layer is a surface accumulation of debris formed on dentine during instrumentation. It is composed of organic and inorganic components and forms both a superficial, loosely adherent, layer and a deeper, tightly adherent, layer. This is a complicating factor when bonding to cut dentine.

It is 0.5 – 5 microns in thickness.
It is variably attached to the dentine surface.
It is generally contaminated with bacteria.
Originally it was thought of as a protective barrier reducing permeability of the dentine and protecting the pulp.
Now it is considered to interfere with adhesion.

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10
Q

What are the requirements of a dentine bonding agent?

A
  • Ability to flow
  • Potential for intimate contact with dentine surface
  • Low viscosity
  • Adhesion to substrate (mechanical, chemical and van Der Waals adhesion).
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11
Q

What is the chemical bonding of dentine at a molecular level?

A

Mineralised- Ionic.

Organic- Covalent.

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12
Q

Define critical surface energy.

A

The surface tension of a liquid that will just spread along the surface of a solid. A liquid must have a lower surface energy than the surface it is being placed on for it to flow onto it and stick.
A low surface energy liquid will spread on a higher surface energy substrate because this leads to a lower surface energy of the material as a whole.

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13
Q

What do dentine bonding agents do to dentine in relation to the critical surface energy?

A

Wet dentine has a low surface energy, lower than composite filling materials.
For composite resin to stick to dentine you must make the surface of the dentine have a higher critical energy than the composite.
Dentine bonding agents increase the surface energy of the dentine surface and allow composite to flow and stick to the surface.
They are SURFACE WETTING AGENTS.

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14
Q

Name examples of total etch.

A

Total etch completely removes the smear layer.

  • Scotchbond multipurpose
  • Clearfil photo bond
  • Optibond FL
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15
Q

Name examples of total etch dentine bonding agent and what are the components of it?

A

Total etch completely removes the smear layer.

  • Scotchbond multipurpose
  • Clearfil photo bond
  • Optibond FL

Dentine conditioner: An acid, usually 35% phosphoric.
Primer: Really the adhesive part of the agent with a hydrophilic/hydrophobic molecule
Adhesive: A resin which penetrates into the surface of the dentine attaching to the primers hydrophobic surface.

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16
Q

PRIMER IN DENTINE TOTAL ETCH BONDING AGENT?

A

The primer is really the adhesive element in the process. A coupling agent (HEMA, MDP, GPDM).
It has a bifunctional molecue with a hydrophilic end to bond to the hydrophilic dentine surface and a hyrdophobic, methacrylate end to bond to the resin.
The molecule must also have a spacer group to make it long enough to be flexible when bonding. Lack of flexibility reduces bonding sites and bond strength.
This molecule or group of molecules is dissolved in a suitable solvent. Ethanol, acetone or water.
The C=C bond opens and forms a strong covalent bond with the next resin layer.
The hydroxyl COOC2H4_OH group can combine with similar polar groups on the hydroxyapatite and can react with amine groups on the collagen protein

17
Q

Adhesive in dentine bonding agent?

A

-Bis GMA and HEMA.
Hydrophobic. It may contain some filler particles to make it stronger.
It will contain Camphorquinone to allow it to light cure.

18
Q

Adhesive in dentine bonding agent?

A

-Bis GMA and HEMA.
Hydrophobic. It may contain some filler particles to make it stronger.
It will contain Camphorquinone to allow it to light cure.
Adhesive
Penetrates the primed dentine which now has a hydrophobic surface.
Forms a micromechanical bond within the tubules and exposed dentinal collagen fibres.
MOLECULAR ENTANGLEMENT
Forms the HYBRID LAYER of collagen plus resin.

19
Q

What are the problems with total etch?

A

-Over etching- to collapse the collagen fibres so no resin can penetrate and too deep an etch and the primer cannot penetrate to the full depth of the etch. Moisture dependent:
Too dry and the dentine surface collapses
Too wet and the primer is diluted  reduced strength

20
Q

What happens if the tooth is over dried before applying dentine bonding agent?

A

Collapsed dentine decrease in porosity
Decrease in porosity  poor penetration of
dentine by primer  poor bond

21
Q

The primer and sealer are combined in a single bottle and applied to the etched, washed dentine and light cured. What chemicals are in this bottle?

A

HEMA (others include GDPM and MDP), BIS GMA, alcohol/acetone (solvent) and camphorquinone.

22
Q

How does self etch work?

A

These materials work in a different way from all the previous materials.
They do not attempt to remove the smear layer. They infiltrate it and incorporated themselves into it.
They are not washed off.
This removes the problem of how dry to make the dentine.
Not as technique sensitive but bond doesn’t seem to be as strong to all tooth tissues.