Biology Chp 4 Flashcards
Carbon is the basis for all biological molecules
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- Carbon can form up to four bonds
- Carbon bond with carbon results in carbon skeletons
- Commonly bonds to nitrogen, hydrogen, and oxygen
Organic Chemistry
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the study of compounds containing carbon or organic compounds
organic compounds range from simple molecules to colossal ones
Stanley Miller’s Experiment
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Conclusion: Complex organic molecules could arise spontaneously under conditions thought at that time to have existed on early Earth/abiotically
- abiotic synthesis of organic compounds could have been early stage in the origin of life
Characteristics of an atom
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- e-configuration is key
- determines the kinds and number of bonds an atom will form with another atom
- valence e- are the e- available to form bond with other atoms
Bonds with Carbon
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- Carbon has 6 e- and 4 valence e-
- Usually shares its valence e- with other atoms, resulting in 8e- in its valence shell (covalent bonds)
- Usually forms single or double covalent bonds in organic molecules
When a carbon forms four single bonds, the arrangement of its 4 hybrid orbitals cause the bonds to angle towards the corners of an imaginary tetrahedron
Valence
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The electrons required to fill an atom’s valence shell
Shape variation in carbon chains
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one important source of molecular complexity and diversity that characterize living matter
Hydrocarbons
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Organic molecules consisting of only hydrogen and carbon. Can undergo reactions that release a relatively large amount of energy
Four ways carbon skeletons can vary
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Length, branching, double bond position, and presence of rings
Hydrophobic compounds
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have a great majority of relatively nonpolar carbon to hydrogen linkages
Isomers
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compounds that have the same numbers of atoms of the same elements but different structures and hence different properties
Three Types:
- Structural, cis-trans (aka geometric), and enantiomers
Structural Isomers
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isomers that differ in the covalent arrangements of their atoms
may also differ in the location of double bonds
ex.) pentane and 2-Methylbutane C5H12
Cis-Trans Isomers (AKA Geometric Isomers)
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Carbons have covalent bonds to the same atoms, but these atoms differ in their spacial arrangements due to the inflexibility of double bonds
- double bonds do not permit same level of rotation as single bonds
Cis isomer (X atoms/group of atoms on same side), Trans isomer (X atoms/group of atoms on opposite sides)
Enantiomers
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Isomers that are mirror images of eachother and that differ in shape due to the presence of an assymetric carbon. If one exists the other has to exist, not necessarily equally. Carbon must be bonded to four different groups
Thalidomide (R - anti-nausea) (S - causes birth defects)
What affects a molecule’s shape and function?
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Differing chemical groups along the carbon skeleton’s arrangement
ex.) estradiol and testosterone