Biochemistry Exam 1 Flashcards

1
Q

Hydrophobic interaction between non polar molecules

A

require the presence of surrounding water molecules

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2
Q

If pK values for phosphoric acid are 2.15, 6.82, and 12.38, at what PH would one observe equal amounts of H2PO4-, and HPO42-

A

6.82

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3
Q

What is the ph of a solution with a OH- of 4.1 x 10^-3 M

A

11.61

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4
Q

The pH at the midpoint in the titration of an acid with a base is

A

equal to the pK of the corresponding acid

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5
Q

Which of the following statements about water is not true?

A

in the liquid state it is only 15% less hydrogen bonded than in the solid state at 0 degrees celsius

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6
Q

The capacity of buffer to resist changes in pH upon addition of protons or hydroxide ions depends on

A

all of the above (the pea, the ph, the total concentration)

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7
Q

In a hydrogen bond between a water molecule and another biomolecule,

A

The hydrogen bond will typically form between a hydrogen atom and either a nitrogen, sulfur, or oxygen atom

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8
Q

The ph of coffee is 5.6. The pH of grapefruit juice is 2.6. This means that the proton concentration in coffee is

A

1000 times lower than In grapefruit juice.

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9
Q

What is the conjugate base in the product of the following reaction

A

H2SO4-

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10
Q

Molecules such as methanol and ethanol are very soluble in water because

A

They contain 0-H groups that can form multiple H bonds with water

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11
Q

The 104.5 bond angle in the water molecule is the results of the _ arrangement of electron orbitals around oxygen

A

Tetrahedral

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12
Q

When considering O,N, and F, the shortest hydrogen bond with -OH group would be formed with _ since this atom is the most _ in the group.

A

F, and electronegative

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13
Q

A strong acid is completely ionized in water, where as weak acid is

A

only partially ionized

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14
Q

Which of the following is a physical property of water that results from hydrogen bonding?

A

all the above ( high boiling, a solid state, high surface tension, the ability to solubilize polar molecules

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15
Q

A sample of gastric juice has a PH of 1.20. What is the concentration of hydronium ion in this sample?

A

6.3 x 10-2 M

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16
Q

Which of the following shows the buffer that is found in the bloodstream?

A

H2CO3= HCO3- +H+

17
Q

What is the final pH if you have 700 ml of a sodium acetate buffer and you add 10 ml of 1 M NaOH

A

5.85