Benzene Flashcards
What is position 1 called in benzene?
ipso
What is position 2 called in benzene?
ortho
What is position 3 called in benzene?
meta
What is position 4 called in benzene?
para
Describe the bonding in benzene
Sp2 hybridized C atoms
Delocalised π-e-
Planar molecule
Each C has 120 degrees bond angle
What is 1st stage of Ar-Se?
Energy rises as E+ approaches
= interacts with π-system
What is 2nd stage of Ar-Se?
π-system disrupted in 1st transition state
Partial sigma-bond between 1 ring of C + incoming E+
What is 3rd stage of Ar-Se?
From 1st transition state reaction proceeds to form sigma complex = Wheland intermediate
What is 4th stage of Ar-Se?
Wheland contains Sp3 hybridized C
What is the final stage of Ar-Se?
2nd transition state contains partial bond to H
Loss which = rearomatization
Wheland intermediate resonance forms + graph
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