Benzene Flashcards

1
Q

What is position 1 called in benzene?

A

ipso

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2
Q

What is position 2 called in benzene?

A

ortho

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3
Q

What is position 3 called in benzene?

A

meta

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4
Q

What is position 4 called in benzene?

A

para

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5
Q

Describe the bonding in benzene

A

Sp2 hybridized C atoms
Delocalised π-e-
Planar molecule
Each C has 120 degrees bond angle

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6
Q

What is 1st stage of Ar-Se?

A

Energy rises as E+ approaches

= interacts with π-system

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7
Q

What is 2nd stage of Ar-Se?

A

π-system disrupted in 1st transition state

Partial sigma-bond between 1 ring of C + incoming E+

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8
Q

What is 3rd stage of Ar-Se?

A

From 1st transition state reaction proceeds to form sigma complex = Wheland intermediate

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9
Q

What is 4th stage of Ar-Se?

A

Wheland contains Sp3 hybridized C

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10
Q

What is the final stage of Ar-Se?

A

2nd transition state contains partial bond to H

Loss which = rearomatization

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11
Q

Wheland intermediate resonance forms + graph

A

LEARN

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