Basic Soil Properties Flashcards
Anion
- negatively charged atom or molecule
- Examples found in soils
- phosphate (H2PO4-, HPO42-)
- sulfate (SO42-)
- nitrate (NO3-)
- chloride (Cl-)
- ions carry 1, 2, or 3 charges called monovalent, divalent, trivalent
Cation
- positively charged atom or molecule
- Examples in soils:
- Calcium (Ca2+)
- magnesium (Mg2+)
- sodium (Na+)
- potassium (K+)
- ammonium (NH4+)
- ions that carry one, two, or three charges are called monovalent, divalent, or trivalent.
Cation exchange capacity
- Cation exchange capacity is that amount of positively charged cations which can be held by a given weight of soil.
- Cations are held by negative charges in clay and organic matter.
- units
- centimole charge per kg soil (cmolc/kg soil)
- which is equivalent to meq/100g soil.
Soil has a CEC of 10 cmolc/kg
What is the CEC per meq/100g soil?
10 meq/100g soil
10 cmolc/kg = 10 meq/100g soil
Anion Exchange Capacity (AEC)
- Anion exchange capacity is that amount of negatively charged cations which can be held by a given weight of soil.
- Anions are held by charges positive charges in clay and organic matter.
- units are the same as CEC
Soil organic matter (humus) CEC content
200 meq/100g
Vermiculite Clay CEC
150 meq/100g
Montmorillonite Clay CEC
100 meq/100g CEC
Illite Clay CEC
30 meq/100g CEC
Kaolinite Clay CEC
10 meq/100g
Soil Contains
- 3% clay
- 20% montmorillonite
CEC of 26 meq/100g
(0.03x200 + 0.20x100)
As pH increases. . .
. . .CEC increases and AEC decreases
*most important in weathered soils of tropical climates
Some clay minerals have holes that fit. . .
. . . K+ and NH4+ ions.
- when those ions enter the holes, the clay collapses around them making them more plant available
- weathering reactions can slowly release these cations to more available forms
Parent material and minerology influence on background fertility
- determines many soil properties which influence background fertility
- pH
- CEC, AEC
- soluble salts
- Clay minerology
- organic matter
- insoluble minerals also serve as a nutrient resevoir that can become plant available over time
Saline Soil
- contains sufficient soluble salt to impair plant growth
- electrical conductivity greater than or equal to 0.4 siemens per meter in saturation extract.
Sodic / Natric Soil
- has from 13 to 15 percent (or more) of the CEC occupied by sodium
- have poor structure and accompanying poor plant growth
Saline-Sodic Soils
- soils have ECs > 0.4 siemens per meter and from 13 to 15 percent of the CEC (or more) occupied by sodium.
- these soils have good physical properties until the salt is removed and they revert to sodic soils.
Calcareous Soils
soil that contains free calcium carbonate (CaCO3)