basic revision and concept Flashcards
identify the s block that has the highest first ionization energy
Be
trend of ionisation
ionisation increases across the period and down the group
trend of first ionisation across the period
There is a general increase in first Ionisation Energies of the elements across a period, with two exceptions. Aluminium and Sulphur are the exceptions in Period 3. Boron and Oxygen are the exceptions in Period 2.
electron configuration for copper and chromium
it has removed as 4S1 and 3d5….
trend of ionisation energy with exception in period 2 Be Configuration s2
B Configuration p1
The first e- removed from Be is from a 2s sub level.
- The first e- removed from B is from a 2p sub level.
- The 2s sub level is lower in energy than 2p.
- Therefore less energy is needed to remove the electron from B.
trend of ionisation
N Configuration p3 O configuration p4
The first e- removed from N is from a 2p sub level and is unpaired.
- The first e- removed from O is also from a 2p sub level, but is from a paired orbital.
- This means O has a lower ionisation energy due to electron pair repulsion.
- Therefore less energy is needed to remove the electron from O.
period 3
Mg Configuration s2 Al Configuration p1
The first e- removed from Mg is from a 3s sub level.
- The first e- removed from Al is from a 3p sub level.
- The 3s sub level is lower in energy than 3p.
- Therefore less energy is needed to remove the electron from Al.
first ionisation trend
P Configuration p3 S Configuration p4
The first e- removed from P is from a 3p sub level and is unpaired.
- The first e- removed from S is also from a 3p sub level, but is from a paired orbital.
- This means Sulfur has a lower ionisation energy due to electron pair repulsion.
- Therefore less energy is needed to remove the electron from S