Basic Concepts and Hydrocarbons Flashcards

1
Q

What is nomenclature?

A

The naming system for compounds

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2
Q

What is a homologous series?

A

A series of organic compounds that have the same functional group with successive members differing by CH2

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3
Q

What is a functional group?

A
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4
Q

Features of a homologous series - Aliphatic, Alicyclic and Aromatic:

A
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5
Q

Alkanes:

A
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6
Q

Isomers of C4H10

A
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7
Q

Alkenes:

A
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8
Q

Isomers of C4H8

A
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9
Q

What are saturated compounds?

A

Saturated compounds have only single bonds

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10
Q

What is the general formula?

A

The simplest algebraic formula for a homologous series

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11
Q

What is a displayed formula?

A

A displayed formula shows the relative positions of atoms and the bonds between them

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12
Q

What is a structural formula?

A

A structural formula provides the minimum detail for the arrangement of atoms in a molecule

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13
Q

What are unsaturated compounds?

A

Organic compounds that contain at least one carbon=carbon (double) covalent bond

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14
Q

What is a skeletal formula?

A

A simplified structural formula drawn by removing hydrogen atoms from alkyl chains

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15
Q

What are hydrocarbons?

A

Hydrocarbons are compounds that contain only hydrogen atoms and carbon atoms

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16
Q

What is a molecular formula?

A

A molecular formula shows the numbers and type of the atoms of each element in a compound

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17
Q

Structural isomers:

A

Structural isomers are compounds with the same molecular formula but different structural formulae

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18
Q

Stereoisomers:

A

Stereoisomers are compounds with the same molecular and structural formulae, but a different arrangement of atoms in space

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19
Q

Naming E or Z isomers:

A
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20
Q

Naming cis/trans isomers:

A
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21
Q

Alcohols:

A
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22
Q

Isomers of C4H10O:

A
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23
Q

Carbonyl compounds - Aldehydes and Ketones:

A
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24
Q

Isomers of C4H8O:

A
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25
Q

Isomers of C5H10O:

A
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26
Q

Carboxylic Acids and Esters:

A
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27
Q

Isomers of C4H8O2:

A
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28
Q

Haloalkanes:

A
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29
Q

General formulae of alkanes, alkenes and alcohols:

A
30
Q

Shapes of molecules in an organic context:

A
31
Q

What are alkanes?

A

Alkanes are a homologous series of saturated hydrocarbons

32
Q

Bonding of alkanes:

A
33
Q

Shape of alkanes:

A
34
Q

Alkanes’ feature of a homologous series:

A
35
Q

Melting and boiling points of alkanes:

A
36
Q

The effects of chain length and branching on the melting and boiling points of alkanes:

A
37
Q

Reactions of alkanes:

A
38
Q

Combustion and incomplete combustion:

A
  • Complete combustion is oxidising a fuel in a plentiful supply of air
  • Incomplete combustion is oxidising a fuel in a limited supply of air
39
Q

Combustion of alkanes:

A
40
Q

Halogenation of alkanes:

A
41
Q

Reaction of methane and chorine:

A
42
Q

Mechanism - (free) radical substitution: CH4 + Cl2

A
43
Q

Limitations of radical substitution:

A
44
Q

What is a radical?

A
45
Q

What is homolytic fission?

A
46
Q

Substitution reactions:

A
47
Q

Sigma (σ) bonds:

A
48
Q

Pi (π) bonds:

A
49
Q

Functional group of alkenes:

A

C=C

50
Q

What is an unsaturated hydrocarbon (like alkenes) ?

A
51
Q

Cycloalkenes:

A
52
Q

Reactivity of alkenes:

A
53
Q

Reaction of alkenes with bromine (halogenation):

A
54
Q

Reactions of alkenes with hydrogen (hydrogenation):

A
55
Q

Reactions of alkenes with hydrogen halides:

A
56
Q

Markovnikoff’s rule (e.g. propene + HBr):

A
57
Q

Reactions of alkenes with steam (hydration):

A
58
Q

Mechanism of alkenes and halogens:

A
Electrophilic Addition
59
Q

What is an electrophile?

A
(the mechanism of ethene and bromine)
60
Q

What is an addition reaction?

A
61
Q

What is a carbocation?

A
62
Q

What is heterolytic fission?

A
63
Q

Mechanism of alkenes and hydrogen halides (propene and HBr):

A
Electrophilic Addition
64
Q

What is a monomer?

A

A monomer is a small molecule that combines with many others to form a long chain polymer

65
Q

What is a polymer?

A

A polymer is a long chain molecule made from many monomers

66
Q

What is addition polymerisation?

A

Addition polymerisation is when the monomers are alkene molecules, and so the π-bonds open up, and many of them add together to form a long chain

67
Q

Polymers:

A
68
Q

Equations of polymers:

A
69
Q

Problems of polymer waste:

A
70
Q

Sustainable ways to process waste polymers include:

A
71
Q

How are toxic waste products (HCl) removed?

A
72
Q

Alternatives to polymers - and advantages of these alternatives:

A