Basic Concepts and Hydrocarbons Flashcards
What is nomenclature?
The naming system for compounds
What is a homologous series?
A series of organic compounds that have the same functional group with successive members differing by CH2
What is a functional group?
Features of a homologous series - Aliphatic, Alicyclic and Aromatic:
Alkanes:
Isomers of C4H10
Alkenes:
Isomers of C4H8
What are saturated compounds?
Saturated compounds have only single bonds
What is the general formula?
The simplest algebraic formula for a homologous series
What is a displayed formula?
A displayed formula shows the relative positions of atoms and the bonds between them
What is a structural formula?
A structural formula provides the minimum detail for the arrangement of atoms in a molecule
What are unsaturated compounds?
Organic compounds that contain at least one carbon=carbon (double) covalent bond
What is a skeletal formula?
A simplified structural formula drawn by removing hydrogen atoms from alkyl chains
What are hydrocarbons?
Hydrocarbons are compounds that contain only hydrogen atoms and carbon atoms
What is a molecular formula?
A molecular formula shows the numbers and type of the atoms of each element in a compound
Structural isomers:
Structural isomers are compounds with the same molecular formula but different structural formulae
Stereoisomers:
Stereoisomers are compounds with the same molecular and structural formulae, but a different arrangement of atoms in space
Naming E or Z isomers:
Naming cis/trans isomers:
Alcohols:
Isomers of C4H10O:
Carbonyl compounds - Aldehydes and Ketones:
Isomers of C4H8O:
Isomers of C5H10O:
Carboxylic Acids and Esters:
Isomers of C4H8O2:
Haloalkanes:
General formulae of alkanes, alkenes and alcohols:
Shapes of molecules in an organic context:
What are alkanes?
Alkanes are a homologous series of saturated hydrocarbons
Bonding of alkanes:
Shape of alkanes:
Alkanes’ feature of a homologous series:
Melting and boiling points of alkanes:
The effects of chain length and branching on the melting and boiling points of alkanes:
Reactions of alkanes:
Combustion and incomplete combustion:
- Complete combustion is oxidising a fuel in a plentiful supply of air
- Incomplete combustion is oxidising a fuel in a limited supply of air
Combustion of alkanes:
Halogenation of alkanes:
Reaction of methane and chorine:
Mechanism - (free) radical substitution: CH4 + Cl2
Limitations of radical substitution:
What is a radical?
What is homolytic fission?
Substitution reactions:
Sigma (σ) bonds:
Pi (π) bonds:
Functional group of alkenes:
C=C
What is an unsaturated hydrocarbon (like alkenes) ?
Cycloalkenes:
Reactivity of alkenes:
Reaction of alkenes with bromine (halogenation):
Reactions of alkenes with hydrogen (hydrogenation):
Reactions of alkenes with hydrogen halides:
Markovnikoff’s rule (e.g. propene + HBr):
Reactions of alkenes with steam (hydration):
Mechanism of alkenes and halogens:
What is an electrophile?
What is an addition reaction?
What is a carbocation?
What is heterolytic fission?
Mechanism of alkenes and hydrogen halides (propene and HBr):
What is a monomer?
A monomer is a small molecule that combines with many others to form a long chain polymer
What is a polymer?
A polymer is a long chain molecule made from many monomers
What is addition polymerisation?
Addition polymerisation is when the monomers are alkene molecules, and so the π-bonds open up, and many of them add together to form a long chain
Polymers:
Equations of polymers:
Problems of polymer waste:
Sustainable ways to process waste polymers include:
How are toxic waste products (HCl) removed?
Alternatives to polymers - and advantages of these alternatives: