Basic Chemistry Flashcards

Periodic table, reaction types, etc.

1
Q

Valence electron periodic table trend

A

Increase from left to right and from top to bottom

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2
Q

Metals

A

-Elements on the left side and middle of the table
-Good electrical conductors
-Usually solid under standard conditions
-Ductible and malleable (can be stretched into other shapes)

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3
Q

Nonmetals

A

-Elements on the far right side of the periodic table
-Poor conductors

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4
Q

Metalloids

A

-Narrow staircase region on periodic table
-Poor to decent conductors
-Brittle

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5
Q

Metalloids (specific elements)

A

Boron, silicon, germanium, arsenic, antimony, tellurium

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6
Q

Group 1 Elements

A

Alkali metals; 1 valence electron; very reactive

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7
Q

Group 2 Elements

A

Alkaline earth metals; 2 valence electrons; reactive

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8
Q

Group 3-12 Elements

A

Transition metals; readily conduct electricity; most have multiple oxidation states; hard and durable

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9
Q

Group 13 Elements

A

First is metalloid boron, rest are metals; 3 valence electrons

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10
Q

Group 14 Elements

A

Carbon family; 4 valence electrons

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11
Q

Group 15 Elements

A

Nitrogen family; 5 valence electrons

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12
Q

Group 16 Elements

A

Chalcogens; 6 valence electrons, form -2 anions

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13
Q

Group 17 Elements

A

Halogens; 7 valence electrons; very reactive

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14
Q

Group 18 Elements

A

Noble/Inert gases; full valence shell; noreactive

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15
Q

Effective nuclear charge (Zeff)

A

Attractive force of the atom’s nucleus on the atom’s valence electrons

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16
Q

Effective nuclear charge periodic trends

A

Increases from left to right, decreases from top to bottom due to shielding

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17
Q

Atomic radius periodic trends

A

Decreases from left to right, increases from top to bottom (inverse relationship with Zeff)

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18
Q

Electrostatic repulsion

A

Electrons repel each other and want to be far away from each other, so radius increases for anions compared to neutral atom

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19
Q

Ionization energy

A

Energy required to remove one valence electron from a neutral atom in the gaseous state (first is always lower than the second due to reduced electrostatic repulsion after removal of first)

20
Q

Ionization energy periodic trends

A

Increases from left to right, decreases from top to bottom

21
Q

Main energy source of ATP

A

Energy stored in the third phosphate group’s bond - electrons in the other two phosphate groups strongly repel it

22
Q

Oxidation reactions

A

Loss of electrons; fewer bonds to hydrogen and more to oxygen

22
Q

Reduction reactions

A

Gain of electrons; more bonds to hydrogen and fewer bonds to oxygen

23
Q

Oxidation order of Hydrocarbons

A

Alkynes, Alkenes, Alkanes

24
Polarity
Distribution of charge in a molecule
25
Hydrogen bonding
Strong charge based interactions between partial positive and partial negative charges on O-H, F-N, and N-H
26
Ions
Fully charged atoms or molecules
27
Types of atoms in order of increasing polarity
Nonpolar < Polar but not H-bonding < Molecules that use H-bonding < Ions
28
Steroids
Have polar groups, but are mostly nonpolar (4 ring structure)
29
Amphipathic
Molecule with both polar and nonpolar parts
30
Charge dipole
Formed from charge vectors within molecules, can cancel each other or have a net movement
31
Binary compound
Consists of exactly two different elements
32
Polyatomic ion
Charged species consisting of multiple atoms
33
Intramolecular forces
Hold atoms together
34
Covalent bond
-Bond between two nonmetals -Sharing of valence electrons
35
Nonpolar covalent bond
2 elements in the bond have the same/very similar electronegativity (<0.5 eneg difference)
36
Polar covalent bond
Very different electronegativity values between two elements, resulting in uneven sharing of electrons (0.5-1.7 eneg difference)
37
Ionic bond
Between metal and nonmetal, complete transfer of electrons to nonmetal (>1.7 eneg difference)
38
Metallic bonds
Electrons become delocalized, creating an electron cloud
39
Intermolecular forces
Forces between separate molecules
40
London Dispersion Forces
-Weakest IMF -Can be between any two molecules -Result from chance temporary dipoles -Stronger and more likely in larger molecules
41
Dipole-dipole interactions
Between polar molecules with stable dipoles
42
Hydrogen bonds
Between Hydrogen and either Oxygen, Fluorine, or Nitrogen (especially electronegative) ; both inter- and intra- molecular
43
Ion-dipole forces
Between an ion and a polar molecule
44
Ion-ion forces
IMF between two ions