Baked Products: Batters and Dough Flashcards
Quick Bread Characteristics
- leavened chemically by baking soda/baking powder
- leavening agent = air, steam, CO2
- preparation time: quick
- gluten development: encouraged
- formation of gases before and during baking
Yeast Bread characteristics
- leavened biologically by yeast
- leavening agents: air, steam, CO2
- Preparation time: 2-5 hours
- gluten development: encouraged
- formation of gases during baking
Pour batter liquid:flour ratio
1:1
- Ex. pancake
Drop batter liquid:flour ratio
1:2
- Ex. muffin
Soft dough liquid:flour ratio
1:3
- Ex. biscuit, yeast bread
stiff dough liquid:flour ratio
1:6-8
- Ex. piecrust
- flour-liquid mixtures that are beaten/stirred
- ingredients are incorporated in a considerable amount of liquid as continuous medium
batters
- much thicker than batter
- does not contain a lot of liquid and is kneaded, not beaten or stirred
- flour/gluten matrix is the continuous medium
dough
wheat protein
gliadin and glutenin
corn protein
zein
rye protein
secalin
barley protein
hordein
Flours with gluten-forming potential
wheat, rye, barley flours
an elastic cohesive mass made up of gliadin, glutenin, water, and a lipoprotein compound
wheat gluten
- the water-insoluble protein
- contributes toughness and rubberiness to gluten structure = elasticity
- form Beta-sheet/spiral configuration
glutenin
- the water-insoluble protein
- contributes stickiness and tackiness to gluten structure
gliadin
Characteristics of Gluten
- low water solubility
- has water-binding capacity
- viscoelasticity
Characteristics of viscoelasticity
- hydrogen bonding
- hydrophobic interactions
- sulfhydryl-disulfide interchange reactions, resulting in extensive polymerization of gluten proteins
Bonds formed by gliadins
intramolecular disulfide bonds contribute viscosity
Bonds formed by glutenins
intermolecular disulfide bonds contribute elasticity
Formation of gluten
- upon hydration and manipulation, two proteins aggregate and form disulfide bridges
- this produces a gluten protein matrix that is subsequently coagulated upon baking
- forms three-dimensional structure capable of stretching without breaking
Effect of too much kneading
gluten network may break with overextension
Flours with gluten-forming potential
hard wheat, rye, barley
Flours without gluten-forming potential
oat, corn, rice, soy
- due to inherent differences in protein composition
Gluten-Free Labeling Rule
A food labeled “gluten-free” does not contain any of the following:
- ingredient that is wheat, rye, barley, crossbred hybrid (prohibited grains)
- ingredient derived from prohibited that hasn’t been processed to remove gluten
- ingredient that is derived from a prohibited grain and that has been processed to remove gluten if use of ingredient results in presence of 20 PPM + of gluten in food
Function of flour in batters and doughs
- provides protein: gluten-forming, elasticity and structure
- provides starch: gelatinizes, more rigid crumb, source of fermentable sugar used by yeast to produce CO2 for leavening
Properties of hard wheat
- high gluten-forming potential
- absorbs more water
- Ex. Bread flour
- tougher
Properties of soft wheat
- less gluten-forming proteins
- absorbs less water
- Ex. cake flour
- softer
- Derived from endosperm of milled wheat
- most common flour used to prepare baked goods
wheat flour
- contains all three kernel parts: endosperm, germ, bran
- bran’s sharp edges cut through developing protein structure —–> lower volume baked product
whole wheat flour
- layered, outer coat of a kernel (14.5% of weight)
- outside pericarp layer: protects the seed
- inside layer: includes the seed coat
- contains insoluble dietary fiber, b vitamins, and trace minerals
Bran
- Part of the grain that provides energy for the seed
- contains carbohydrates, some protein, and some B vitamins
- lowest fat content
- highest protein content
- greatest percentage of kernel
- primarily starch
Endosperm
- Part of the grain that provides nourishment for the seed
- contains B vitamins, Vitamin E, minerals, and phytochemicals
- composes 2.5% of seed
- where sprouted begins
- highest lipid content, may lead to rancidity from lipoxidase or non-enzymatic oxidation
- composes 8% of protein and most of thiamin (B1)
Germ
Definition of whole-grain foods
A) a food providing at least 8 g of whole grains/ 30g serving
B) consist of intact, ground, cracked, flaked or otherwise processed kernel after the removal of inedible parts (hull and husk). All anatomical components must be present in the same relative proportions as in the intact kernel
Characteristics of finely ground whole wheat flour
- less sharp edges that cut and can reduce volume
- due to presence of bran, percentage of protein is lower in whole wheat flour than in refined wheat flour
- contains germs that may cause rancidity over time
Factors that affect final product texture
- wheat flour and non-wheat flour
- Sift standardizes the amount of flour added to a formulation and assures consistency in product preparation
- same brand of flour is milled in different milling locations
Function of liquids in batters and doughs
- hydrate proteins required for gluten formation and gelatinization of starch
- solvent for dissolving ingredients
- produces steam that leavens and expands air cells during baking
Federal regulations of bread water level
Water level of finished commercially prepared bread loaf may not exceed 38%
Function of lactose from milk in batters and doughs
- produces softer crumb
- holds moisture in product
- contributes flavor and color from Maillard browning
Function of whey proteins from milk in batters and doughs
- results in diminished volume and poor quality
Function of leavening agents in batters and doughs
- to raise dough
- to make product light and porous
- ex. air, steam, CO2
Characteristics of air as a leavening agent
- involved in all baked products
- amount of air depends on: mixing, sifting, amount of air incorporated into raw product
- incorporation: creaming fat and sugar, beating eggs, sifting, folding airy egg into mixture
- after introduction into food, air cells expand with heat, a different leavening agent diffuses into space and enlargens
Characteristics of steam as a leavening agent
- produced from liquid ingredients (milk, juice, water, eggs)
- partially leavens ALMOST EVERYTHING
- HIGH LIQUID-TO-FLOUR RATIO and HIGH OVEN TEMPERATURE are needed for WATER VAPORIZATION and dough expansion in products mainly leavened by steam
- characteristics: high volume, hollow interior
- expand cell size
- make batters and dough light and porous
- holes in the crumb may be large or small
- holes may be intact or exploded
Characteristics of CO2 as a leavening agent
- major leavening agent in batters and doughs
- amount required in a formulation is proportional to the amount of flour
- more flour = more ingredient for CO2 production = more CO2 produced
- timing: if batter/dough is left unbaked for extended time period = bad // if gluten structure is not sufficiently developed to allow extension with the CO2
- two production routes = chemical and biological
- agents fill existing air cells and gluten structures that expand with the CO2 they produce
Function of Egg yolk in batters and doughs
emulsifier that distributes fat in the batter
Function of egg white in batters and doughs
contributes to aeration and leavening when beaten due to presence of air cells that are filled with CO2 / expanded by steam
Function of egg proteins in batters and doughs
coagulate by heat, beating, or a change in pH —-> contributes to structure
Function of whole egg in batters and doughs
contributes to flavor, color, and nutritional value
Function of fat in batters and dough
- coats flour proteins, physically interferes with gluten development —> tenderization
- contribute flakiness
- minimize length of developing gluten protein platelets (shortens)
- help prevent staling process of baked products
Function of oils in batters and doughs
- coats flour proteins, physically interferes with gluten development —> tenderization
- contribute tenderness
- minimize length of developing gluten protein platelets (shortens)
- help prevent staling process of baked products
Function of plastic fats in batters and doughs
- may be spread/molded to shape
- do not pour
Function of polyunsaturated oils in batters and doughs
- yield a more tender, mealy, crumbly product than saturated fats
- b/c oil covers larger surface area of flour, helps control/limit water absorption
Function of salt in batters and doughs
- dehydrates yeast cells
- controls growth of yeast with CO2 production
- osmotic effect
Effect of absence of salt on batters and doughs
- allows rapid yeast development and rapid rising
- produces collapsible, porous structure, overstretched broken gluten strands
Effect of more salt on batters and doughs
- compete with other substances for water absorption
- less water for gluten development and starch gelatinization
- salty flavor of baked products
Sugar: Tenderization Function
- competitively absorbs water
- less water available for gluten formation/starch gelatinization
- elevates protein coagulation temperature —–> extends time for CO2 to expand
Sugar: Fermentation Function
- sugar acts as substrate for the yeast organism to act upon
- produces CO2, acids, alcohols, and other compounds
- artificial sweeteners cannot be fermented
Sugar: Color function
- reducing sugars (lactose) provide browning due to Maillard Reaction
- Caramelization
Functions of Sugar in batters and doughs
- tenderization
- fermentation
- color
- flavor and mouthfeel
Function of the amount of sugar in batters and doughs
- small amount: good for yeast bread fermentation
- large amount: dehydrates yeast cells and reduces dough volume
Function of honey in batters and dough
- imparts varied flavors
- makes sweeter and moister baked product because of fructose
- fructose is sweeter and more hygroscopic than sucrose
Function of sugar substitutes in batters and doughs
- provide sweetness
- don’t provide FUNCTIONAL PROPERTIES OF SUGAR
Function of molasses in batters and doughs
- imparts its own character flavor that may be very strong
- more acidic than sugar
- should not be used to replace more than half of total amount sugar
Leavening process of baked products
- occurs when the air spaces/gluten structure is filled with leavening agent
- gas: air, steam, carbon dioxide
Characteristics of chemically-produced CO2 leavening agent
- produced by reaction of baking soda (sodium bicarbonate) and an acid (wet or dry)
- baking soda used alone reacts quickly with heat and CO2
- CO2 may escape from the raw batter before it is able to leaven
- baking soda must be combined with liquid acid or dry acid
- goal: delay production of CO2 and prevent escape form mixture
Liquid acids used in CO2 production via chemical production
vinegar (acetic acid)
HCl
applesauce
buttermilk
juices
vinegar
Dry acids used in CO2 production via chemical production
cream of tartar = potassium bitartrate
Composition of baking powder
- sodium bicarbonate = baking soda
- dry acid
- inert cornstarch filler
Purpose of cornstarch filler in baking powder
keeps soda and acid from reacting with each other prematurely and standardizes weight in the baking powder canister
Requirement of baking powders
must yield at least 12% available CO2 gas by weight
- Ex. 100g baking powder must yield 12g of CO2
- classification of baking powder
- How quickly they react with water and heat to form CO2
- most of commercial baking powder is double-acting
action rate
- soluble acids release CO2 almost immediately upon moistening/mixing with liquid at room temperature
- Ex. monocalcium phosphate
Single-Acting Powder
- Releases CO2 two times:
1. The first occurs as the mixture is moistened
2. The second occurs as mixture is heated - Ex. SAS phosphate: sodium aluminum sulfate phosphate
Double-Acting Powder
Result of Excessive CO2 production
- cell walls may be stretched and break
- results in coarse-textured, low volume product
- soapy flavor
- yellow crumb
- overly browned exterior
Result of too little CO2 production
- product is NOT SUFFICIENTLY LEAVENED
- finished baked product is soggy with a compact grain of small air cells in the batter/dough
Baking Soda Characteristics
- ingredients: pure sodium bicarbonate
- function: single-acting
- common use: cookies
- function requirements: acid
Baking powder characteristics
- ingredients: sodium bicarbonate, dry acid, inert cornstarch filler
- function: single and double acting
- common uses: cakes muffins, pies, biscuits
- function requirements: wet and heat
the biological process in which the microorganisms (bacteria or yeast) function to metabolize fermentable organic substances
fermentation
- the bacteria responsible for forming sourdough bread
- the bacteria function to degrade maltose —–> yield acetic and lactic acid and produce CO2
Lactobacillus sanfrancisco
- microscopic, one-celled fungi
- plant without stems/chlorophyll that grows by budding
- releases zymase
Saccharomyces cerevisiae
the process of growth in which a new cell grows and comes from an existing cell
budding
an enzyme that metabolizes fermentable sugars in an anaerobic process, yielding ethanol and CO2
zymase
Fate of ethanol produced by fermentation during baking
volatilized
How is Saccharomyces cerevisiae fermentation process (warm water and sugar) affected by temperature
- 105-115 F : each yeast cell rehydrates and buds, producing new cells
- > 130F: thermal death
- low temp: yeasts are ineffective
Effect of sugar in biologically leavened doughs
- due to osmotic pressure, more time is needed to leaven sweetened yeast dough
- possible that leavening may use chemical leavens along with the yeast with high levels of sugar
Spices that increase yeast activity
- cardamom
- cinnamon
- ginger
- nutmeg
Spices that decrease yeast activity
- dry mustard
Optional yeast bread ingredients
- spices
- fat
- sugar
Required yeast bread ingredients
- yeast
- liquid
- salt
- flour
Function of flour in yeast bread
- should have gluten potential
- contribute to adequate gluten development and viscoelasticity
- starch gelatinization also contributes to structure
- starch (partially converted to sugar) is the substrate for yeast
Function of liquid in yeast bread
- necessary to hydrate flour proteins, starch, and yeast cells
- milk/water warmed to 105-115F —> allows yeast cells to bud
- higher/lower temps destroy/don’t activate yeast
Function of salt in yeast bread
- added for flavor
- helps control gluten development —–> so gluten stretches sufficiently but not too much
Function of sugar in yeast bread
increases fermentation speed
Function of fat in yeast bread
provides flavor and tenderness
Function of alpha-amylase in yeast bread
- yields glucose
- produces fermentable sugar
- Bread produced when mixing all the ingredients and bake immediately without a waiting period
- leavened chemically by baking powder, baking soda, and steam
Quick Bread
Examples of quick breads
- biscuits
- loaf bread
- muffins
- pancakes
- popovers
- waffles
Function of flour in quick breads
provides adequate gluten structure
Function of milk/water in quick breads
- disperse medium
- leaven by forming steam
Function of eggs in quick breads
- coagulation to provide structure
- impart nutritive value and color
Function of oil in quick breads
- coats flour granules, covers them to prevent water absorption
Function of sugar in quick breads
- provides sweetness and tenderization
- assists in Maillard browning
Characteristics of soft wheat cake flour and function in cakes
- soft flour particles are small in size
- cake is loftier and tender with a finer grain than hard flour with its higher gluten-forming ability
Characteristics of bleached flour and function in cakes
- pigment is whiter
- baking performance is improved
- this is because bleaching oxidizes the surface of the flour grains and weakens the protein, limiting gluten development
Function of liquid in cakes
- gelatinize starch
- hydrate protein and starch
Function of egg white in cakes
- beaten to incorporate air
- function as emulsifier
Function of oil in cakes
- tenderize the product
Function of sugar in cakes
- compete for water
- inhibits both gluten development and starch gelatinization
General rule in cake production
MINIMIZE GLUTEN DEVELOPMENT
Purpose of mixing
- to distribute ingredients, including leavening agents
- to equalize the temperature throughout a mixture
Doughs that are kneaded
- biscuits
- pastries
Batters that are stirred
- cakes
- muffins
- pour batters
Mixing Method in Biscuits
- cut solid fats into pea size into sifted dry mixture
- all of liquid added
- ball is formed
- dough is kneaded: to develop gluten and orient the direction of gluten strands
Kneading time:
- underkneading: biscuit fails to rise sufficiently
- Overkneading: overproduces gluten and results in smaller volume, tougher biscuit —-> will not rise evenly because CO2 escapes through weak location in gluten structure
Mixing Methods in Cakes
- cream plastic fat with sugar: provides aeration
- Egg added
- Dry and wet ingredients alternately
Mixing Methods for muffins
- use the drop batter method
1. pour all liquid ingredients into all of sifted, dry ingredients, and mix minimally - overmixing: high gluten-potential batter develops long strands of gluten and results in formation of tunnels/peaks in the muffin
- Tunnels: hollow internal pathways, form long strands of gluten, allowing gases to escape from the interior
Mixing Methods for Pour batters
- ex. pancakes, popovers, waffles = foods with high proportion of liquid to flour, don’t require a definite manner of mixing
- overmixing is unlikely to affect shape/texture because high level of water and low level of gluten development
Mixing method for yeast dough
- kneading
- Ferment
- Punch Down
- Resting
- Shaping
- Proofing the dough
Function/Characteristics of kneading in yeast doughs
- stretch and develop the elastic-like gluten
- incorporates and subdivides air cells
- promotes evenness of temperatures throughout the dough
- removes excess CO2
- distributes the leavening agent
- press dough down
- fold in half
- give dough half-turn between each pressing and folding
Accomplished by: heavy duty mixer, bread machine, person!
Underkneading/no gluten: less/no gluten strands —-> breads with less volume
Overkneading: gluten strands may break, result in less elastic mass of dough —> fails to rise satisfactorily
Function/Characteristics of Fermentation (1st rise) in yeast doughs
- fermentable sugar converted into ethanol and CO2
- then the rise is complete, dough has doubled in size
- dough is left to rest so gluten strands rest or relax
- fermentation continues and gluten network becomes easier to manipulate
Function of punching down in yeast doughs
- beneficial because it allows heat of fermentation and CO2 to escape
- this introduces more oxygen and controls the size of air cells —–> prevents overstretching and collapse of gluten
Function/Characteristics of Fermentation (2nd rise) in yeast doughs
- dough is shaped and allowed to rise again
- dough with double in volume as many more yeast cells have budded and produced more CO2
Characteristics of unbaked batters/doughs
foams of watery substances surrounding air cell
Protein changes during baking
harden/coagulate by heat
Starch granule changes during baking
lose birefringence, swell, and gelatinize
Gas changes during baking
expand and produce leavening
Water changes during baking
evaporates
Alcohol changes during baking
by-product of yeast fermentation evaporates, but not completely
Flavor and aroma changes during baking
they do?
Altitude-adjusted baking
- every 1000 ft change in elevation up/down changes the boiling point by approximately 2F
- at high elevations, a reduction in sugar and less leaven is needed
- reduction in sugar: less competition for water —-> more water available to develop stronger gluten structure
- Less leaven: prevents overexpansion of dough that may easily occur with lower atmospheric pressure
Proper Storage of Baked Products
- extension of shelf life
- maintains best flavor and texture
- cover and eliminate external air
- good wrap/airtight storage
Nutritive Value of Baked goods
- varies according to type/amount of ingredients used in formulation
- some may be prepared with reduction in fat (product will be less tender and flavorful)
Microbial Hazards in batters and doughs
Bacterial: Bacili
Mold
Bacterial Microbial Hazards in batters and doughs
- Bacili bacteria from crop was obtained to produce flour
- presence causes syrupy/ropelike interior of bread
- acidic environment (pH 5-4.5) prevents the growth of bacteria
- Ex. sodium/caclium propionate, sodium diacetate
- commonly added to commercially prepared bread to inhibit mold and bacteria
Mold inhibitors
Nonmicrobial hazards in batters and doughs
- Rancidity
- Staling
- Caused by fat/oil oxidation
Rancidity
- all changes occurring after batters and doughs are baked
- primarily involves recrystallization of amylopection
- change in flavor
- harder/less elastic crumb
- less water-absorbing ability
Staling