Atoms, Electrons & Chemical Bonding Flashcards

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1
Q

Atomic Number

A

Number of protons in the nucleus

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2
Q

Mass number

A

Sum of protons + neutrons in the nucleus

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3
Q

Isotopes

A

Same number of protons, different number of neutrons

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4
Q

How was wave particle duality discovered?

A

Schrodinger combined the idea that an electron has wave properties with classical equations of wave motion to give a wave equation for the energy of an electron in an atom

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5
Q

What does wave equation give?

A

A series of solutions called wave functions

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6
Q

Quantum numbers

A

A whole number which specifies the shell and is related to the energy of the orbital

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7
Q

Angular Momentum Quantum Number

A

Usually designed by a letter (s,p,d,f) and describes the shape of the orbital

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8
Q

Nodal surface

A

A region where the probability of finding an electron is zero

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9
Q

What do s orbitals increase with?

A

The number of nodal surfaces

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10
Q

Pauli Exclusion Principle

A

No 2 electrons in the same atom can have the same set of 4 quantum numbers

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11
Q

Shape of p orbitals

A

Dumbells

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12
Q

When do p orbitals become possible?

A

When the quantum number, n = 2 and higher

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13
Q

What is an ionic bond formed between?

A

Metals and nonmetals with very different electronegativity

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14
Q

Properties of Ionic bonds

A

Conductors and have high melting points

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15
Q

Electronegativity

A

The measure of the ability of an atom to attract a pair of electrons

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16
Q

How does electronegativity differ across the periodic table?

A

Increases across the period

Decreases down the group

17
Q

Most electronegative element

A

Fluorine

18
Q

Least electronegative element

A

Francium

19
Q

What are covalent bonds formed between?

A

nonmetallic elements of similar electronegativity

20
Q

Bonds in all polyatomic ions and diatomics

A

Covalent bonds

21
Q

What draws atoms closer together in covalent bonds?

A

The mixing of energy sublevels

22
Q

Bond energy

A

The energy required to break a covalent bond, which is the same as the amount of energy released when the bond is formed

23
Q

Non-polar covalent bonds

A

When electrons are shared equally

24
Q

Polar Covalent bond

A

When electrons are shared but unequally

25
Q

Properties of Metals

A

Good conductors, lustrous, high melting points

26
Q

Octet rule

A

The tendency for atoms to seek 8 electrons in their outer shell

27
Q

Electron Dot Formulas

A

The number of dots around each atom is equal to the number of valence electrons the atom has

28
Q

When does a sigma bond occur?

A

When the bonding orbitals point along the axis connecting the two bonding nuclei

29
Q

When does a pi bond occur?

A

When the bonding orbitals are parallel to each other and perpendicular to the axis connecting the two bonding nuclei

30
Q

Why are sigma bonds stronger than pi bonds?

A

The interaction between parallel orbitals is not as strong between orbitals that point at each other

31
Q

Resonance

A

The two shared electron pairs consitute a double bond

32
Q

Resonance

A

The two shared electron pairs consitute a double bond