Atomic Theory 2: periodic trends, chemical bonding, and molecular structures Flashcards

1
Q

What do the electrostatic forces of attraction and repulsion do

A

influences properties such as atomic size, ionization energy, and electronegativity

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2
Q

Atomic size down group

A

Increases when moving down a group
Number of shells increase, so valence electrons are farther from nucleas.

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3
Q

What is the shielding effect

A

Repulsion be e- from lower shells, increases atomic size

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4
Q

Atomic size across period

A

Decreases moving left to right across a period
Number of protons in the nuclear increase = more electrostatic force, electrons pulled closer to nuclear
More e- than protons = harder to pull them to center

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5
Q

What is electronegativity

A

The ability for an atom to draw bonding e- to itself, affected by atomic number and radius

Bigger atoms = less electronegativity
Smaller atoms = more electronegativity

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6
Q

Electronegativity down group

A

Decreases moving down a group
The valence shell is farther from the nuclear, so less attraction between nucleus and e-

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7
Q

Electronegativity across a period

A

Increases moving lef tot right across a period
The more protons added to nuclear, the stronger the pull on e-

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8
Q

What is ionization energy

A

The energy required to remove a valence e- from a neutral atom

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9
Q

Ionization energy across a period

A

Increases left to right across a period
Increase in e- and protons = greater force of attraction = more energy needed to remove them

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10
Q

Ionization energy down a group

A

Decreases moving down a group
Shielding effect (more e- to repel) weakens the force between the valence e- and the nucleus

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11
Q

What do negative electron cloud do

A

Exert repulsive forces

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12
Q

how does a chemical bond form

A

If the attractive forces between the atoms are stronger than the repulsive forces, the two atoms are in a state of lower energy (stable) then when they were apart

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13
Q

What is an ionic bond

A

A bond between two atoms with a big difference in EN, occurs bc of the metals low ionization energy and ENs

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14
Q

Where is the force of attraction in a covalent bond

A

Between a pair of e- and 2 adjacent positive nuclei, all species are electrically neutral

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15
Q

Example of nonpolar covalent bond

A

Hydrogen and hydrogen, EN difference is close to 0 = density of e- cloud is centered between the nuclei

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16
Q

What are polar covalent bonds

A

Covalent bonds between atoms with different EN, results in an unequal sharing of bonding electrons, resulting in a dipole

17
Q

What is a dipole

A

A partial negative pole and a partial positive pole