Atomic Theory 2: periodic trends, chemical bonding, and molecular structures Flashcards
What do the electrostatic forces of attraction and repulsion do
influences properties such as atomic size, ionization energy, and electronegativity
Atomic size down group
Increases when moving down a group
Number of shells increase, so valence electrons are farther from nucleas.
What is the shielding effect
Repulsion be e- from lower shells, increases atomic size
Atomic size across period
Decreases moving left to right across a period
Number of protons in the nuclear increase = more electrostatic force, electrons pulled closer to nuclear
More e- than protons = harder to pull them to center
What is electronegativity
The ability for an atom to draw bonding e- to itself, affected by atomic number and radius
Bigger atoms = less electronegativity
Smaller atoms = more electronegativity
Electronegativity down group
Decreases moving down a group
The valence shell is farther from the nuclear, so less attraction between nucleus and e-
Electronegativity across a period
Increases moving lef tot right across a period
The more protons added to nuclear, the stronger the pull on e-
What is ionization energy
The energy required to remove a valence e- from a neutral atom
Ionization energy across a period
Increases left to right across a period
Increase in e- and protons = greater force of attraction = more energy needed to remove them
Ionization energy down a group
Decreases moving down a group
Shielding effect (more e- to repel) weakens the force between the valence e- and the nucleus
What do negative electron cloud do
Exert repulsive forces
how does a chemical bond form
If the attractive forces between the atoms are stronger than the repulsive forces, the two atoms are in a state of lower energy (stable) then when they were apart
What is an ionic bond
A bond between two atoms with a big difference in EN, occurs bc of the metals low ionization energy and ENs
Where is the force of attraction in a covalent bond
Between a pair of e- and 2 adjacent positive nuclei, all species are electrically neutral
Example of nonpolar covalent bond
Hydrogen and hydrogen, EN difference is close to 0 = density of e- cloud is centered between the nuclei