Atomic Structure And The Periodic Table Flashcards

1
Q

Radius of an atom

A

0.1 nanometers

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2
Q

Nucleus of an atom

A
  • middle of the atom
  • contains protons and neutrons
  • radius of around 1x10^-14m (1/10,000 of the radius)
  • positive charge from the protons
  • almost the whole mass is concentrated in the nucleus
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3
Q

Electrons

A
  • move around nucleus in electron/energy shells
  • negatively charged and tiny; cover a lot of space
  • volume of orbits determines size of the atom
  • virtually no mass
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4
Q

Why do atoms have a neutral charge?

A
  • same number of protons and electrons
  • charges cancel out
  • if number of protons and electrons are not equal, it is known as an ion
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5
Q

Atomic Number

A

Number of protons in one atom of an element

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6
Q

Mass Number

A

Total number of protons and neutrons in the atom

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7
Q

Element

A
  • substance that contains atoms all with the same number of protons
  • e.g. all hydrogen atoms have 1 proton
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8
Q

Isotope

A
  • different form of the same element, which has the same number of protons but a different number of neutrons
  • same atomic number but different mass numbers
  • e.g. C-12 has 6 protons and 6 neutrons but C-13 has 6 protons and 7 neutrons
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9
Q

Relative Atomic Mass

A

Average mass, taking into account the different masses and abundances (amounts) of all the isotopes that make up the element

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10
Q

Relative Atomic Mass Formula

A

Ar = sum of (isotope abundance x isotope mass number) / sum of abundances of all the isotopes

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11
Q

Compounds

A
  • substances formed from two or more elements
  • atoms of each element are in fixed proportions
  • held together by chemical bonds
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12
Q

Reactants & Products

A
  • reactants are on the left side of the equation
  • elements/compounds at the beginning of the reaction
  • products are on the right side of the equation
  • elements/compounds at the end of the reaction
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13
Q

Why must symbol equations be balanced?

A
  • must be the same number of atoms on each side of the equation
  • numbers put in front of formulas, as formula of compound cannot be changed
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14
Q

Mixture

A
  • elements and compounds that are not chemically bonded
  • can be separated by physical methods
  • properties are the same as the properties of separate parts; no chemical properties are affected
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15
Q

Chromatography

A
  • used to separate out different dyes in an ink
    1. Draw a pencil line at the bottom of a sheet of filter paper
    2. Add a spot of ink and place in a beaker of solvent e.g. water
    3. Solvent seeps up the paper (capillary action) carrying the ink with it
    4. More soluble dyes travel further up the paper and vice versa, so they will separate out
    5. End result is a series of spots, called a chromatogram
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16
Q

Filtration

A
  • used to separate insoluble solids from a liquid in a mixture
  • also used in purification (removes solid impurities)
  • uses filter paper and a funnel
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17
Q

Evaporation / Crystallisation

A
  • separating a soluble solid from a liquid in a mixture
  • gently heat the mixture until the liquid has completely evaporated
  • very quick method of separation
  • leave in evaporating dish to evaporate naturally
  • forms crystals (hence the name) of the solid
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18
Q

Separating Rock Salt

A
  1. Grind the mixture to ensure it will dissolve easily
  2. Stir the mixture in water - salt will dissolve, but sand/rock won’t
  3. Filter the mixture. Grains of sand can’t pass through tiny holes in filter paper, so they will be left behind as residue
  4. Evaporate the water, until it leaves dry crystals of salt
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19
Q

Simple Distillation

A
  1. Used to separate a liquid out of solution
  2. Solution is heated; lowest BP evaporates first
  3. Vapor is cooled, condensed and collected
  4. Rest of solution left behind in flask
    - limitations: can only separate two liquids; both liquids must have very different BPs
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20
Q

Fractional Distillation

A
  1. Heat solution with fractionating column on top
  2. Different BPs evaporate at different temperatures
  3. Lowest BP first; reaches top of column when thermometer reads its BP
  4. Column cooler towards top - higher BPs can’t reach top at this stage
  5. When first liquid collected, raise the temperature for the next liquid
    e. g. separating crude oil
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21
Q

Dalton’s model of the atom

A
  • described atoms as solid spheres

- different spheres made up different elements

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22
Q

Thomson’s model of the atom

A
  • atoms aren’t solid spheres
  • measurements of charge and mass show that atom must contain smaller, negatively-charged particles - electrons
  • plum pudding model (ball of positive charge with electrons dotted around in it)
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23
Q

Alpha particle scattering experiment

A
  • Rutherford and student, Marsden
  • particles should pass through or be slightly deflected
  • some were deflected more than expected; a few deflected backwards
  • devised nuclear model of the atom, key point being lots of empty space
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24
Q

Rutherford’s model of the atom

A
  • also known as nuclear model of the atom
  • tiny, positively charged nucleus at centre, where most of mass concentrated
  • ‘cloud’ of electrons surround nucleus; most of atom is empty space
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25
Q

Bohr’s model of the atom

A
  • elaboration for Rutherford’s nuclear model
  • discovered that ‘cloud’ of electrons would collapse due to attraction to nucleus
  • atoms must be contained in shells
  • electrons orbit in fixed shells and aren’t anywhere in between
  • ## each shell is a fixed distance from the nucleus
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26
Q

Discovery of protons and neutrons

A
  • Rutherford discovers protons
  • further experiments, dividing hydrogen nucleus into smaller particles
  • each smaller particle had same charge as hydrogen nucleus
  • Chadwick discovers neutron
  • experiments provide evidence for ‘neutral particle’
  • almost same mass as proton, but no charge
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27
Q

Energy shell rules

A
  1. Electrons always occupy shells (aka energy levels)
  2. Lowest energy levels are always filled first; closest to nucleus
  3. Only certain number of electrons in each shell (first shell has 2, second has 8, third has 8, fourth has 18…)
  4. Atoms are ‘happier’ when they have full electron shells, like the noble gases
  5. Most atoms don’t have full outer shells, so they must react to fill it
28
Q

Early Periodic Table

A
  • no knowledge of protons or neutrons, so there was no atomic number to them
  • could only measure relative atomic mass, so they were arranged in order of atomic mass
  • periodic pattern noticed in the properties of elements
  • early tables were incomplete and had some elements inaccurately placed, as properties and proton number were not taken into account
29
Q

Mendeleev’s Periodic Table

A
  • arranged elements with various gaps
  • mainly ordered by atomic mass, but switched some elements to fit groups based on properties
  • gaps left for undiscovered elements; he accurately predicted their properties, as they fit the pattern
30
Q

Modern Periodic Table

A
  • ordered by increasing atomic (proton) number
  • there are repeating patterns in properties
  • metals on left and non-metals on right
  • elements with similar properties form columns, known as groups
  • group number tells you number of electrons in outer shell (this determines reactive properties of element)
  • trends in reactivity and properties found in most groups
  • rows are called periods, and they represent another full shell of electrons
31
Q

Metals

A
  • form positive ions when they react
  • towards the bottom and left of the table
  • most elements are metals
  • mostly the same properties, as they all have metallic bonding
32
Q

Non-metals

A
  • mostly form negative ions when they react
  • at the far right and top of the table
  • wide range of chemical property; involved in different types of bonding
33
Q

Transition Metals

A
  • centre of the periodic table
  • typical metals: good electrical and thermal conductors, very dense, strong and shiny
  • can have more than one ion
  • ions are coloured, so they form colourful compounds
  • compounds often make good catalysts
34
Q

Group 1

A
  • Lithium, Sodium, Potassium, Rubidium, Caesium, Francium
  • soft with low density (first three are less dense than water)
  • one electron in outer shell, which makes them very reactive and have similar properties
  • increasing reactivity down the group
  • decreasing MPs and BPs down the group
  • easily form ionic compounds, that will be white compounds, that dissolve in water to form a colorless solution
35
Q

Group 1 reactions

A
  • all react in similar ways (sodium is used here as an example)
  • sodium + water => sodium hydroxide + hydrogen
  • sodium + chlorine =>sodium chloride
  • different types of oxide can form depending on type of group 1 metal
  • lithium + oxygen => lithium oxide (Li2O)
  • sodium + oxygen => sodium oxide (Na2O) OR sodium peroxide (Na2O2)
  • potassium + oxygen => potassium peroxide (K2O2) OR potassium superoxide (KO2)
36
Q

Group 7

A
  • increasing reactivity up the group
  • higher melting points down the group
  • Fluorine is a poisonous, yellow gas
  • Chlorine is a poisonous, dense green gas
  • Bromine is a dense, poisonous, red-brown volatile liquid
  • Iodine is a dark grey crystalline solid or a purple vapor
  • exist as diatomic molecules
  • seven electrons in outer shell; react similarly
37
Q

Group 0

A
  • noble gases, includes helium, neon argon, etc.
  • eight outer electrons - full outer shell
  • don’t react, as they don’t need to fill their shells
  • exist as monatomic gases
  • colourless gases at room temperature
  • noble gases are inert, so they aren’t flammable
  • increasing BPs down the group
38
Q

Explain the trend in reactivity of group 1 metals

A
  • more reactive down the group
  • more electron shells between nucleus and outer shell
  • shielding electrons
  • further from nucleus; weaker electrostatic force of attraction
  • loses electrons more easily, so reacts easier
39
Q

Explain the trend in reactivity in group 7 metals

A
  • more reactive up the group
  • less electron shells between outer shell and nucleus
  • less shielding electrons
  • closer to nucleus; stronger force of electrostatic attraction
  • gains electrons more easily, so reacts easier
40
Q

Explain lack of reactivity of noble gases

A
  • full outer shells
  • must have incomplete outer shell in order to react
  • unable to gain/lose electrons
  • can’t react with any other atoms
41
Q

Relative Mass of a Neutron

A

1

42
Q

True or False? Element only contain atoms with the same number of protons

A

True

43
Q

Define relative atomic mass

A

Number of neutrons and protons in the nucleus of an atom

44
Q

Give the formula for carbon dioxide

A

CO2

45
Q

Give the formula for Sodium carbonate

A

Na2CO3

46
Q

Give the formula for Hydrochloric acid

A

HCl

47
Q

What is the difference between a compound and a mixture?

A

Compound: two or more chemically bonded elements/substances
Mixture: two or more elements/substances that are not chemically bonded

48
Q

Name of the pattern of spots generated by paper chromatography

A

Chromatogram

49
Q

Method used to separate insoluble solid from a liquid

A

Filtration

50
Q

Describe the process of fractional distillation

A
  • gradually heated to each boiling point
  • lowest BP evaporates to top of fractionating column, where it is cooled, condensed and collected
  • heat and repeat for each liquid
51
Q

Who demonstrated that the plum pudding model is incorrect?

A

Ernest Rutherford, with the alpha particle scattering experiment

52
Q

What did Bohr’s model of the atom suggest?

A

Electrons are organised into regular energy shells (orbitals) at set distances from the nucleus of the atom

53
Q

Electronic structure of helium

A

2

54
Q

Electronic Structure of Carbon

A

2.4

55
Q

Electronic Structure of Sodium

A

2.8.1

56
Q

Why did Mendeleev leave gaps in his periodic table?

A

He organised his table by properties, so he continued ordering by mass and switched elements or left gaps where he knew the properties did not match the groups they were in

57
Q

What name is given to the vertical columns in the periodic table?

A

Groups

58
Q

What does the group number indicate?

A

The group number shows how many electrons are in the outer shell of each element in the group

59
Q

Where are non-metals on the periodic table?

A

Top right of the table

60
Q

Give three properties which are specific to transition metals

A
  • form differently charged ions
  • form coloured ions and compounds
  • often make good catalysts
61
Q

State three trends in group 1 elements going down the group

A

Increasing Reactivity
Decreasing melting and boiling points
Higher relative atomic mass

62
Q

State the products of the reaction between sodium and water

A

Sodium Hydroxide and Hydrogen

63
Q

State three differences in properties between group 1 elements and transition metals

A

Transition metals are harder
Group 1 elements are more reactive
Transition metals have higher melting and boiling points

64
Q

Describe the trend in boiling point going down group 7

A

Increasing boiling (and melting) points down the group

65
Q

How many atoms are in each molecule of a halogen?

A

2 - they exist as diatomic molecules

66
Q

What charge do halogen ions form when they react with metals?

A

-1

67
Q

Trend in boiling point down group 0

A

Boiling points increase down the group