atomic structure Flashcards

1
Q

atomic nucleus stucture

A

all atoms have a positively charged nucleus surrounded by a larger cloud of negatively charged electrons
the nucleus is made up of two subatomic particles- protons and neutrons

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2
Q

mass and charge

A

AMU- atomic mass units
The subatomic particles have a certain mass and charge. The nucleus is overall positive as it is composed of positive protons, neutral neutrons, disregard the mass of an electron as it is negligible

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3
Q

proton and neutron mass

A

1 AMU

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4
Q

where are electrons with low energy

A

Electrons with low energy are in shells close to the nucleus

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5
Q

where are electrons with high energy

A

electrons with high energy are in the outer shells, electrons in the same shell have about the same emergy

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6
Q

max number of electrons calculation

A

the max number of electrons that a shell can hold can be calculated using 2n^2

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7
Q

what is Aufbau

A

The aufbau principle states that lower energy shells must fill before higher ones

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8
Q

valence electrons

A

the outermost shell is the valence shell

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9
Q

what can the valence shell predict

A

can predict the chemical properties of the element and the bonds it will form because valence electrons are used in chemical reactions

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10
Q

octet rule

A

atoms lose, gain and share electrons to achieve 8 valence electrons

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11
Q

protons - notation

A

the no. of protons is the atomic number (Z)

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12
Q

what is the mass number why is it a decimal

A

protons + neutrons (A)

mass number is decimal because of isotopes, rnd to nearest whole number

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13
Q

what is no. of protons equal to

A

protons= electrons

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14
Q

how to find no. of neutrons

A

mass number- atomic number

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15
Q

notation

A

mass number top

atomic number bottom

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16
Q

what r isotopes

A

atoms that have the same number of protons (atomic number) but different number of neutrons as known as isotopes. In nature atoms have different numbers of isotopes ie. gold has one isotope

17
Q

Electronic structure- quantum mechanical model

A

major energy levels in an atom are called shells (n), the max number of shells 2n^2

these shells contain separate energy levels of similar energy called subshells labelled s,p,d and f, each holding a certain no. of electrons

18
Q

how many electrons in each subshell?

A

s - 2
p - 6
d - 10
f - 14

19
Q

electronic structure

A

electrons therefore exist within subshells which themselves are within shells

eg.
shell 1 (n=1), there is only an s subshell holding max 2 electrons 
shell 2 (n=2), there is an s AND p subshell that hold 2 & 6 electrons, so the total electron number for n=2 is 8
20
Q

orbitals

A
hold 2 electrons
s- 1 orbital 
p- 3 orbitals 
d- 5 orbitals 
4s has less energy than 3d so aufbau says 4s will fill before 3d
21
Q

chromium and copper- exceptions to the rule

A

chromium - more stable to have a completely half filled d and ignore aufbau

copper - more stable to have a completely filled 3d and ignore aufbau

correct filling order- 4s then 3d
correct shell config. 3d then 4s

22
Q

orbital diagrams

A

orbital diagrams show individual electrons in their orbital boxes in their subshells, to help show the electron config. of an atom

23
Q

what is the pauli exclusion principle

A

no two electrons can occupy the same quantum position or state. Electrons in the same orbital must have opposite spin

24
Q

what is hunds rule

A

every orbital in a subshell is singly occupied before any orbital is double occupied