atomic structure Flashcards
define mass number
sum of protons and neutrons in a atome
define atomic number
number of protons in an atom
how to find the neutron number?
-mass number- atomic number
define relative atomic mass
-mr= mass number of an atom of an element/1/12 x mean mass of C-12isotope
what is mass spec used for?
-used to identify different isotopes and find the overall relative atomic mass of an element
how does time of flight mass spec show isotope number?
-records the time taken for each isotope to reach the detector
what occurs in the ionisation step?
-ELECTROSPRAY IONISATION= the sample is dissolved and pushed through a small nozzle at high pressure, a voltage is applied, causing each particle to gain a H+ ion, sample is turned into a GAS made up of positive ions.
ELECTRON IMPACT= the sample is vaporised and a ‘electron gun’ is used to fire high energy electrons at it, knocking one electron off each particle so they gain +1 ions
what happens in the acceleration step?
-positively charged ions are accelrated by electric feild so THEY ALL HAVE THE SAME KE.
what happens in the ion drift step?
-the ions enter a region with no electric feild so they just drift. LIGHTER ions will drift FASTER, than heavier ones
what happens in the detection stage?
-as lighter ions travel faster than heavier ions, they reach the detector in LESS time than heavier ions. the detector detects charged particles and a mass spec is producved?