Atomic orbitals and electronic config Flashcards
What are the different shapes of orbitals?
s,p,d and f
Name all of the quantum numbers, giving their letters
principal quantum number, n
angular momentum quantum number, l
magnetic quantum number, ml
spin magnetic quantum number, ms
principal quantum number n indicates
the main energy level for an electron and is related to the size of the orbital
the angular momentum number l determines
the shape of the subshell and can have values from 0 to n-1
The magnetic number ml determines
the orientation of the orbital and can have values between -l and +l
The spin magnetic quantum number ms determines
the direction of spin and can have values of -1/2 or +1/2
What is the Aufbau principle?
electrons fill up orbitals in order of increasing energy
What is Hund’s rule?
when degenerate orbitals are available, electrons fill each singly, keeping their spins parallel before spin pairing starts
What is the Pauli exclusion principle?
No two electrons in an atom can have the same set of 4 quantum numbers, therefore, no orbital can hold more than 2 electrons and these 2 electrons must have opposite spin
There is a special stability associated with
half-filled and full subshells
Electron pair repulsions decrease in strength in the order:
non bonding pair/non bonding pair >non bonding pair/bonding pair>bonding pair/bonding pair