Atomic models & the periodic table Flashcards
Chapter 1
What is an atom?
An atom is the smallest unit of ordinary matter that forms a chemical element.
What is an element?
An element is a pure substance (only one type) that cannot be broken down into simpler/smaller units using chemical reactions.
Element vs atom example
For example, water (H2O) is composed of 2 hydrogen atoms and one oxygen atom.
An element is a collection of atoms of the same type
Dalton (DESCRIBE)
Solid sphere model, 1803
Thomson (DESCRIBE)
Plum pudding model, 1897
Rutherford (DESCRIBE)
Nuclear model, 1911
Planetary model (DESCRIBE)
Bohr 1913
Simplified atomic model (DESCRIBE)
Chadwick, 1932
Solid sphere model
John Dalton described atoms as tiny particles that could not be divided.
Dalton had no idea of the size of atoms or how they were constructed. His model was called the Solid Sphere Model.
From who did Dalton take his idea?
He took this basic idea from Democritus, who used the word “atomos” to describe the smallest possible piece of matter.
Describe J.J Thomson’s experiment
Thomson experimented with cathode ray tubes, cutting edge technology of his time.
Strong potential differences (voltage) between two metal plates cause electrons to be ejected from the cathode plate.Thomson was able to deflect the electrons using electric fields.
What did J.J. Thomson conclude from his experiment?
Thomson was able to deflect the electrons using electric fields, demonstrating that the particles had negative charge.
How did Thomson modify Dalton’s model?
Thomson modified Dalton’s model to better explain his findings.
Atoms must contain smaller negative particles, electrons.
Electrons can be removed from atoms.
What was the problem with Thomson’s model?
His problem was that he could not find the positive charge in the atom that would balance the charge of the negative electrons.
Describe the developments in technology that were rapid in 1908 (Ernest Rutherford).
Following cathode rays, scientists quickly discovered how to produce and use many kinds of radiation: x-rays, rays made of alpha, beta, gamma particles.
Scientists experimented with alpha particles, which are much bigger than electrons and have a positive charge.
Describe the gold foil experiment
Rutherford expected most of the alpha particles to pass through the gold foil. It was only 160 atoms thin (0.00004 cm)!
(average human hair = 0.007 cm)
This was mostly true, but every now and then an alpha particle would bounce back, like it hit something much bigger with a strong positive charge.
(remember: like charges repel, similarly to magnetic repulsion)
What is Rutherford’s theory?
Rutherford’s theory is that the nucleus is very dense, and has a positive charge. The electrons revolve around of the nucleus.
His theory was that the atom looked like the solar system with the sun in the middle and the planets revolving around it. His model is called the Planetary Model.
What was the problem with Rutherford’s model?
But many scientists had trouble understanding how the electrons could remain circling around the nucleus.
Since positive and negative charges attract, shouldn’t the electrons eventually crash into the nucleus?
The Collapse of the Atom!
By 1913, scientists knew that …
light was related to the movement of electrons.
They were able to make light by exciting electrons in gas molecules with electric potential (voltage).
Using a prism, light of different wavelength (color) is refracted and viewed separately.
What was Bohr able to understand?
Bohr was able to understand why only certain frequencies of light were being emitted.
Remember, light is emitted from a moving electron.
Since only very specific types (energies) of light were being emitted, the electrons had to be moving in very specific ways too.
What is wrong with Bohr’s model?
Bohr’s is still incomplete. Remember how charges react: unlike charges attract (+ / -); like charges repel (+/+) (-/-).
What did James Chadwick discover?
Building on the work of colleagues across the world, Chadwick discovered the neutron in 1932.
Scientists had discovered a new type of radiation particle that was very energetic, like alpha particles, but it did not carry a charge.
What did the neutron explain?
The neutron eventually helped us understand why the nucleus doesn’t repel itself apart.
Neutrons allow the Strong Nuclear Force to hold the protons in the nucleus together.
Quickly describe Chadwick’s experiment
Performing this experiment on paraffin and gases, Chadwick was able to determine that the new radiation was a neutral (no charge) particle about the same mass as a proton.
Describe Neil’s Bohr experiment
Cr
Chromium