Atmospheric aerosols Flashcards
Typical concentrations (/cm^3 and micrograms/m^3) of particles in arctic, city (europe), rural Europe), ocean and Santiago
Arctic: 10-100, 0-1 City: 1000-100000, 10-100 Rural: 500-5000, 1-100 Ocean: 100-1000, 1-10 Santiago: ?, 10-1000
Primary particle sources
Breaking of waves (<100nm), Resuspension of soil dust (Most mass in the coarse fraction (1-10 µm), but also significant in fine fraction (0.1-1 µm).), Abrasion by vehicles: Road surface, tyres, brakes (large particles), and Combustion (coal, gas, oil, domestic biomass, forest fires) (soot: 30-200 nm, hydrocarbons: 1.5-30 nm), volcanoes, biological particles.
Volatility
Tendency of a gas to condensate on particles. Low volatility want to condensate.
Two sources of particles in the atmosphere
Primary particles (Directly from source) and secondary particles (gas to particle conversion)
Secondary particle formation. Two types
- Condensation of gases on pre-existing particles, so called secondary formation.
- New particle formation (or nucleation) of new particles from gaseous precursors.
Mechanically generated primary particle sources
Breaking of waves, vehicle abrasion, and grinding
Primary particles from combustion, sources.
Volcanoes, forest fires,domestic biomass, coal power plant, biomass power plant, vehicles.
Secondary particle formation, sources
Forest emission, combusted gases, oceanic biota, pack-ice
Secondary particle formation by nucleation, sources
sulfur sources, ammonia sources, organic sources
Breaking of waves
ocean spray when waves break. Water evaporates from droplets in the air. Salt and biological particles are created.
Wind blown dust
Larger particles are blown over the ground, to heavy to lift, Saltation. Sparks movement of other particles that can be airborne
Diesel exhaust
Soot particles released from combustion in engine. After the exhaust pipe cooling causes organic and sulfur to condense on the particles.
Transport between upper and lower troposphere time
about 1 month
Transport between stratosphere and troposphere time
can take years
Transport time around the globe
two weeks