Assignment 7 Flashcards

1
Q

phase change

A

breaking IMFS

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2
Q

chemical reaction

A

breaking bonds

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3
Q

making a bond (energy)

A

gives off

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4
Q

breaking a bond (energy)

A

costs energy

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5
Q

ΔH

A
enthalpy of reaction
change in heat of a system
found by heat of formation
ΔH = Ef - Ei
= Hproducts - Hreactants
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6
Q

Ef

A

final energy (product’s energy)

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7
Q

Ei

A

initial energy (reactant’s energy)

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8
Q

exothermic

A

gives off energy, ΔH is negative, reaction gets hot

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9
Q

endothermic

A

takes (absorbs) energy, ΔH is positive, reaction gets cold

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10
Q

Q (J)

A
transferred heat
Q = mCpΔT
m - mass (g)
Cp - heat capacity (J/gK or J/gC)
ΔT - change in heat (Tf - Ti) (C or K)
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11
Q

heat capacity (Cp)

A

the heat needed to change the temp of 1g by 1degC (1K)
unique to each substance and state
related to IMFs

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12
Q

calorie

A

ener needed to increase temp of 1g by 1degC

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13
Q

heat of fusion (hf)

A

IMF term, unique to each substance
Q = mhf
m - mass
hf - heat of fusion

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14
Q

heat of vaporization (hv)

A

unique to each substance
Q = mhv
m - mass
hv - heat of fusion

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15
Q

is there a temp change during a state change

A

no, because the energy is going into increasing the KE of the particles, so they can change state, not into heating up the substance

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16
Q

Hess’s Law

A

the heat of reactions is the algebraic sum of the subreactions
Qrxn = Q1 + Q2 + Q3…
ΔHrxn = ΔH1 + ΔH2 + ΔH3…

17
Q

enthalpy

A

heat an object or substance contains

18
Q

heat or enthalpy of formation (ΔHf)

A

combination of 2 or more elements to form a non-elemental product
used in lieu of bond energy
heat gained from the formation of the elements

19
Q

if you have a question where a substance goes through a phase change, then

A
you solve for each step of the phase change with the Q equations and add up all the answers
Q = mCpsolidΔT
Q = mhf
Q = mCpliquidΔT
Q = mhv
PV = nRT
20
Q

finding enthalpy using heat of formation

A

given the molecular equations, do a system of equations until you reach the final equation

21
Q

gibbs free energy (ΔG)

A

ΔG = ΔH - (TΔS)

22
Q

entropy

A

how much the energy:temp ratio changes in a system

23
Q

free energy

A

measure of imbalance of energy

24
Q

ΔG = 0

A

equalibrium

forward and reverse equations are spontaneous

25
Q

ΔG is negative

A

extra energy

spontaneous with free energy

26
Q

ΔG is positive

A

need energy

non-spontaneous