Assignment 10: Redox Flashcards
Redox
Oxidation and Reduction (transfer of electrons from one place to another)
Oxidation
Loss of electrons A —> A+2 + 2e-
Reduction
Gain of electrons Cu+2 + 2e- —> Cu
OILRIG
Oxidation Is Loss Reduction Is Gain
anode -
- oxidation
cathode -
- reduction
Reduction Potential Table
A table showing the measure, in volts, of how much the electons flow relative to a standard (SHE: standard hydrogen electrode)
SHE
Standard Hydrogen Electrode 2H+ + 2e- —> H2
spontaneous
positive voltage
non-spontaneous
negative voltage
Reduction Potential Lab
Goal: create your own reduction potential table with lead as standard (0).
- Cu wants to reduce more than Ni, Pb or Zn
- Zn wants to oxidize more than Ni, Pb, Cu
Oxidation Number
Charge on each atom, not the whole molecule
Double Replacement Reaction
Never a Redox Reaction
Oxidation Number for Diatomic Elements
Always 0 because they are sharing electrons with themselves
Finding Oxidation Number
Look at electronegativity first (either least or more electronegative)
Recharging a Battery
In order to recharge, the electrons must be forced to move in the opposite direction
1 mole e- (electrons) =
96500 coulombs
1 amp =
1 coulomb/sec
Direct Current (DC)
electrons flow in one direction only
Alternating Current (AC)
electrons flow in both directions, 60hz cutten switches direction in wall electrics
Balancing Redox Reactions
**remember to balance charge**
two ways:
1) oxidation number method
2) half reaction method
Oxidation Number Method
1) find the oxidation number of each atom
2) determine what is oxidizing and what is reducing and by how many electrons
3) multiply the coefficient that makes the number of electron lossed and gained equal
4) balance other atoms if needed (if in an aqueous solution, add H2O, H+, OH- to balance)
5) check balance of atoms and charge
Half Reaction Method
1) determine what’s oxidized and what’s reduced
2) write them as two separate half-reactions
3) balance each separately for both charge and atoms (if in an aqueous solution, add H2O, H+, OH- to balance)
4) multiply each by the coefficient that allows electrons lost and gained to be equal
5) add and simplify
6) check balance of atoms and charge
Types of Decay
alpha 42α
beta 0-1β
fission
larger nuclei splitting into smaller nuclei
- radioactive particles
fissile
capable of undergoing fission
fusion
smaller nuclei combining into larger nuclei