Aqueous solutions Flashcards

1
Q

Why is H2O a good solvent

A

Because it is polar, it has partial charges due to the dipoles created by H bonding i.e Dipole-dipole intetraction.

  • It stabilises high energy ions in the solution
  • overcomes the attractive forces of the ionic compounds and prevents them from recombining
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2
Q

Why is ice less dense?

A

Because when water freezes, the H bonds also freeze in place, and they move away from each other creating open spaces, causing it to expand and e less dense due to the open space.

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3
Q

Solvation definition

A

Dissociation of ions due to hydration

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4
Q

How does dissolution occur?

A

The charges of the dipoles on water attract the cations and anions of the molecules and pulls them away from each other

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5
Q

Can non-polar gases dissolve in H20?

A

Yes, through the formation of temporary dipoles (when H2O comes close to electron cloud, it repels some e-s, forming a temporary positive dipole and attracts the ions towards it)

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6
Q

Solubility of substances are crucial in the body for:

A

Transport of inorganic mats and gases + transport of drugs

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7
Q

H20 has high surface tension and heat capacity because of?

A

H bonding, the H2O also absorbs and retains heat energy which remains for a while after due to high heat capacity

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8
Q

How do ice skates work?

A

Pressure decreases the freezing point of water, so when lots of pressue applied on a thin blade, ice melts and you glide on a water molecule

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9
Q

Other polar solvents

A

Alcohols, COOH, Amines, Amino acids

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10
Q

What is dissolution?

A

Solute particles become surrounded by solvent ones.

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11
Q

Most ionic compounds dissociate spontaneously

A

yes because of strong H bonds of H2O

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12
Q

Which molecules are easier to deform

A

NPs with larger e- clouds as e-s are further away from nucleus, meaning that nucleus has a weaker hold on the e-s

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13
Q

Why is Dilute H2SO4 a strong acid?

A

It completely dissociated ions in H2O, how strong is how well it dissociates

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14
Q

is special about H bonding?

A

The bonds are strong but are able to be unmade (mediocre strength bonds), helps with biological interactions

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15
Q

Reason for high BPs

A

The more electronegative the element, the stronger the H bond.

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16
Q

How many different forms of ice?

A

14, manipulate the H bonding to change the form

17
Q

Concentration of H2O per litre at 25ºC

A

55 mol Lˆ-1

18
Q

Ice –> water

A

energy applied, in h2o, h bonds are constantly being made and broken

19
Q

How many H2O molecules around Na and Cl ions when dissociated

A

Around 5-7, h2o molecules move in and out

20
Q

Bonds of molecular compounds

A

H bonds

21
Q

Definition of strong in chem

A

To be completely dissociated in a solvent, i.e dilute H2SO4 as compared to conc. H2SO4. conc. H2SO4 has a lot of H bonding going on and it’s not completely dissociated