Appendix G (confirmatory tests lng) Flashcards
identify the cation
Canary yellow ppt when 1 drop 0.1 M KI is added
Ag+
chem formula: AgI
Identify the cation
yellow ppt when 1 drop of 0.1 M KI is added?
Pb2+
Identify the cation
greenish yellow ppt when 0.1 M KI is added
Hg22+
Identify the cation
white ppt when 3 drops 1M NaOH & 3 drops of 0.1 M NaCl is added
Bi3+
Identify the cation
reddish brown ppt when 3 drops of 6M CH3COOH and 2 drops of 0.1M K4Fe(CN)6
Cu2+
Identify the cation
white ppt when 2 drops of 0.1M K4Fe(CN)6 is added
Cd2+
Identify the cation
scarlet red ppt when 1 drop of 0.1M KI is added
Hg2+
Identify the cation
black ppt when 2 drops of 0.1M HgCl2 is added
Sb3+
Identify the cation
red surface is produced when 2 drops of distilled water, 3 drops of 6M NH4OH, and 1 drop of aluminon reagent is added
Al3+
Identify the cation
blue ethereal layer is produced when added with 3 drops of 3% H2O2, 3 drops of conc. H2SO4, and 4 drops of acetone
Cr3+
Identify the cation
white ppt when 2 drops of 0.1M K4Fe(CN)6 is added
Zn2+
Identify the cation
turnbull’s blue ppt when 2 drops of 0.1M K4Fe(CN)6 is added
Fe2+
Identify the cation
blood red sol’n when 2 drops of 0.1M KSCN is added
Fe3+
Identify the cation
azure blue sol’n when 2 drops of 1M NH4SCN & 4 drops of acetone is added
Co2+
Identify the cation
cherry red ppt when 1 drop of conc NH4OH & 3 drops of C4H8N2O2 (alcoholic dimethylglyoxime) is added
Ni2+
Identify the cation
yellow ppt when 1 drop of 0.1M K2CrO4 is added
Ba2+
Identify the cation
yellow ppt when 1 drop of 0.1M K2CrO4, 1 drop of 1M NH4OH, and 1 drop of 95% ethanol is added
Sr2+
Identify the cation
white ppt when 1 drop of 0.1M K2C2O4 is added
Ca2+
Identify the cation
pale yellow crystals when 3-5 drops of zinc uranyl acetate solution is added
Na+
Identify the cation
brown ppt when one drop of 6M NaOH and 2 drops of Nessler’s reagent is added
NH4+
Identify the anion
white ppt when 6M HNO3 and 2 drops of 0.1M AgNO3 is added
Cl-
Identify the anion
reddish brown layer when 10 drops of CH2Cl2 (DCM), 2 drops of 6M H2SO4, and 0.1M KMnO4 (dropwise w/ shaking) is added
Br-
Identify the anion
purple layer when 10 drops of CH2Cl2 (DCM), 2 drops of 6M H2SO4, and 0.1M KMnO4 (dropwise w/ shaking) is added
I-
Identify the anion
blood red sol’n when 2 drops of 0.1 FeCl3 is added
SCN-
Identify the anion
Prussian blue when 2 drops of 0.1 FeCl3 is added
Fe(CN)64-
Identify the anion
black color when a drop of S2- is placed on a silver coin after standing for 2 mins
S2-
Identify the anion
brown ring when 3 drops of 6M CH3COOH, 0.1M FeSO4 (added slowly on sides of tube) is added
NO2-
Identify the anion
reddish brown ppt when 3 drops of HgCl2 is added
CO32-
Identify the anion
CaC2O4 is produced when added w/ 3 drops of 0.1M CaCl2
C2O42-
Identify the anion
silver mirror is produced when 3 drops of 0.1M AgNO3 sol’n and 5 drops of 6M NH4OH is added then heated in a water bath until visible result is obtained
C4H4O62-
Identify the anion
silver mirror is produced when 3 drops of 0.1M AgNO3 sol’n and 5 drops of 6M NH4OH is added then heated in a water bath until visible result is obtained
C6H5O73-
Identify the anion
yellow ppt is produced when 3 drops of ammonium molybdate reagent is added with 6M HNO3 then stirred then mixture is heated on a water bath for 2-3 mins
PO43-
Identify the anion
loss of purple color when 1 drop of 0.1M KMnO4 w/ 5 drops of water & 2 drops of 6M H2SO4 is added
S2O32-
Identify the anion
blye ethereal layer when 3 drops of 3% H2O2, 3 drops of conc. H2SO4, and 4 drops of acetone is added
CrO43-
identify the anion
brown ring is produced when 2 drops of conc. H2SO4 & 0.1M FeSO4 (slowly ulet sa sides ng tube) is added
NO3-
Identify the anion
white ppt when 5 drops of 0.1M KNO3 is heated in a water bath then after heating, 2 drops of 6M HNO3 & 1 drop of 0.1M AgNO3 is added
ClO3-
identify the anion
white ppt is produced when 1 drop of 0.1M Pb(CH3COO)2</sub
SO42-