ap chem Flashcards

1
Q

exo rxns

A

feels hot, heat is product, temp up

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2
Q

endo rxn

A

feels cold, heat is reactant, temp goes down

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3
Q

delta H of rxn

A

bonds broken - bonds formed (reactants - products)

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4
Q

Breaking bonds is

A

endo

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5
Q

Forming bonds is

A

exo

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6
Q

If a rxn is exo, then bonds formed in the ___ are stronger than the ____ bonds

A

products, reactants

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7
Q

If a rxn is endo, then bonds formed in the ___ are stronger than the ____ bonds

A

reactants, products

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8
Q

Increase in moles of gas is

A

+ dS

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9
Q

What is Keq when dG is (-)

A

Keq>1

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10
Q

negative dG is ____ favored

A

product favored, forward rxn

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11
Q

What are rxns not proceeding at a normal rate called?

A

Under kinetic control due to high activation energy

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12
Q

What is the effect of catalysts and inert gases on equilibrium

A

No effect

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13
Q

Higher energy level means

A

Farther away from nucleus, less Columbic attraction, lower 1st ionization energy

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14
Q

Moving right across a row means

A

Increased Zeff, higher nuclear attraction of valence e-, atomic radius decreases, ionization increases

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15
Q

Peak corresponds to

A

Number of e- in subshell

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16
Q

Isotopes have

A

same number of protons but dif number of neutrons

17
Q

Mass spectroscopy measures

A

atomic masses of isotopes

18
Q

Elements in the same group

A

Same vertical column have similar chemical and physical properties

19
Q

Which is smaller cations or anions and why?

A

Cations because valence e- is removed and anions have extra valence e- added which increases repulsions

20
Q

Metals are on the ___ side of the zig zag

A

left

21
Q

Nonmetals are on the ___ side of the zigzag

A

Right

22
Q

Covalent metals are formed when

A

two nonmetals share electrons

23
Q

Carbon makes ___ bonds

A

4

24
Q

What are the diatomic elements

A

H2 N2 O2 F2 Cl2 Br2 I2 (horses need oats for clear brown eyes)

25
Q

Are asymmetrical molecules polar or nonpolar?

A

Polar because dipoles don’t cancel

26
Q

Is lattice energy exo or endo

A

Endo

27
Q

What two factors affect lattice energy?

A

Increases as charge increases, decreases as radius increases

28
Q

Formal charge formula

A

valence electrons - [lone electrons + (1/2)(bonded electrons)]