amount of substances in all papers (3.1.2) Flashcards
what is the relative atomic mass (Ar)?
the average mass of one atom compared to one twelfth of the mass of one atom of carbon 12.
no units.
what is the relative molecular mass (Mr) ?
the average mass of a molecule compared to one twelfth of the mass of one atom of carbon 12.
for covalent compounds
no units
what is the avogadros constant?
the number of particles in a mole.
(6.022x10^23)
how do you work out the number of moles in pure solids and liquids?
moles= mass/Mr
units: grams
mol
how do you work out the number of moles in pure solids and liquids?
moles= mass/Mr
units: grams
mol
how do you work out the mass of 1 mole of pariticles?
avogadros constant X mass of 1 parrticle.
how to work out the number of particles?
number of moles x avogadros constant
how do you convert kPa to Pa?
x1000
how do you convert cm^3 to m^3?
divide by 10^6 or x10^-6
how do you convert dm^3 to m^3?
divide by 10^3 or x10^-3
how do u convert C to kelvins?
add 273
how do you work out the empirical formula and molecular formula from it?
1: set out the elements with
their masses/percentage.
2: divide each mass by their Mr.
3: divide all them by the smallest
value.
4: give whole number ratio in
empirical formula.
5: molecular formula =
n(empirical formula)
explain the water of crystallisation practical (hydrated salt)
- weigh an empty crucible.
- add 2g of hydrated calcium
sulfate to the crucible and
weigh again. - heat with a bunsen burner for
5 mins and let it cool. - weigh the crucible and
contents again. - heat and reweigh again until
you reach a constant mass to
ensure salt has become
anhydrous.
how do you work out atom economy?
mass of desired product
————————————–x100
total mass of reactants
how do you work out percentage yield?
actual mass of product
————————————–x100
maximum theorectical mass of product
why might a chemical reaction not give a 100% percentage yield?
- reactants react in a different way.
- reaction doesnt go to completion, the reaction is reversible.
- some reactant or product is lost during reaction or seperation or purification.
define the concentration of a solution?
- the number of moles of solute in 1dm^3 of solution?
how do you calculate the number of moles in a solute in a given volume?
- moles = concentration x volume
list the steps of titration?
- pipette 25cm^3 of the HCL into the conical flask.
- add the indicator
- fill the buette with the NaOH solution.
- make sure the jet space in the burette in the solution and air bubbles are removed.
- take the initial burette reading
- add the NaOH
- stop adding NaOH when the indicator changes colour and record the final burette reading.
- work out titre volume.
titration
how do you record the volume
decimals
- to 2 d.p
titration
how do you work out the titre volume?
final burette reading - initial burette reading
titration
when do you have concordant results?
- when you have 2 titre volumes within 0.1
titration
why is a conical flask used instead of a beaker?
- to prevent loss of solution from splashing.
titration
why should we only add a few drops of indicator?
- its slightly acidic, too much will interfer with results.
titration
why does adding distilled water not affect titration reading?
- because the number of moles is still the same.
how do you make a standard solution?
- Weigh the crucible.
on a 2 dp balance - Transfer to beaker and reweigh crucible
- Record the difference in mass
- Add 100cm3 of distilled water to the beaker. Use a glass rod to
stir to help dissolve the solid. - Pour solution into a 250cm3 graduated flask via a funnel.
- Rinse beaker and funnel and add washings from the beaker
and glass rod to the volumetric flask. * Make up to the mark with distilled water using a dropping
pipette for last few drops. - Invert flask several times to ensure uniform solution.
how do you work out percentage error?
maximum error
————————-x100
measurement taken
- if 2 measurements need to be taken in order to obtain the vlaue, the maximum error must be doubled.
how can you reduce error in a titration?
- replace measuring cyclinders with pipettes or burettees.
- make the titre volume by:
. increaing volume and concentration of the substance in the conical flask.
. or decrease concentration of the substance in the burette.