amount of substances in all papers (3.1.2) Flashcards

1
Q

what is the relative atomic mass (Ar)?

A

the average mass of one atom compared to one twelfth of the mass of one atom of carbon 12.

no units.

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2
Q

what is the relative molecular mass (Mr) ?

A

the average mass of a molecule compared to one twelfth of the mass of one atom of carbon 12.

for covalent compounds

no units

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3
Q

what is the avogadros constant?

A

the number of particles in a mole.
(6.022x10^23)

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4
Q

how do you work out the number of moles in pure solids and liquids?

A

moles= mass/Mr

units: grams
mol

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5
Q

how do you work out the number of moles in pure solids and liquids?

A

moles= mass/Mr

units: grams
mol

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6
Q

how do you work out the mass of 1 mole of pariticles?

A

avogadros constant X mass of 1 parrticle.

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7
Q

how to work out the number of particles?

A

number of moles x avogadros constant

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8
Q

how do you convert kPa to Pa?

A

x1000

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9
Q

how do you convert cm^3 to m^3?

A

divide by 10^6 or x10^-6

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10
Q

how do you convert dm^3 to m^3?

A

divide by 10^3 or x10^-3

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11
Q

how do u convert C to kelvins?

A

add 273

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12
Q

how do you work out the empirical formula and molecular formula from it?

A

1: set out the elements with
their masses/percentage.
2: divide each mass by their Mr.
3: divide all them by the smallest
value.
4: give whole number ratio in
empirical formula.
5: molecular formula =
n(empirical formula)

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13
Q

explain the water of crystallisation practical (hydrated salt)

A
  • weigh an empty crucible.
  • add 2g of hydrated calcium
    sulfate to the crucible and
    weigh again.
  • heat with a bunsen burner for
    5 mins and let it cool.
  • weigh the crucible and
    contents again.
  • heat and reweigh again until
    you reach a constant mass to
    ensure salt has become
    anhydrous.
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14
Q

how do you work out atom economy?

A

mass of desired product
————————————–x100
total mass of reactants

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15
Q

how do you work out percentage yield?

A

actual mass of product
————————————–x100
maximum theorectical mass of product

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16
Q

why might a chemical reaction not give a 100% percentage yield?

A
  • reactants react in a different way.
  • reaction doesnt go to completion, the reaction is reversible.
  • some reactant or product is lost during reaction or seperation or purification.
17
Q

define the concentration of a solution?

A
  • the number of moles of solute in 1dm^3 of solution?
18
Q

how do you calculate the number of moles in a solute in a given volume?

A
  • moles = concentration x volume
19
Q

list the steps of titration?

A
  • pipette 25cm^3 of the HCL into the conical flask.
  • add the indicator
  • fill the buette with the NaOH solution.
  • make sure the jet space in the burette in the solution and air bubbles are removed.
  • take the initial burette reading
  • add the NaOH
  • stop adding NaOH when the indicator changes colour and record the final burette reading.
  • work out titre volume.
20
Q

titration

how do you record the volume

decimals

A
  • to 2 d.p
21
Q

titration

how do you work out the titre volume?

A

final burette reading - initial burette reading

22
Q

titration

when do you have concordant results?

A
  • when you have 2 titre volumes within 0.1
23
Q

titration

why is a conical flask used instead of a beaker?

A
  • to prevent loss of solution from splashing.
24
Q

titration

why should we only add a few drops of indicator?

A
  • its slightly acidic, too much will interfer with results.
25
Q

titration

why does adding distilled water not affect titration reading?

A
  • because the number of moles is still the same.
26
Q

how do you make a standard solution?

A
  • Weigh the crucible.
    on a 2 dp balance
  • Transfer to beaker and reweigh crucible
  • Record the difference in mass
  • Add 100cm3 of distilled water to the beaker. Use a glass rod to
    stir to help dissolve the solid.
  • Pour solution into a 250cm3 graduated flask via a funnel.
  • Rinse beaker and funnel and add washings from the beaker
    and glass rod to the volumetric flask. * Make up to the mark with distilled water using a dropping
    pipette for last few drops.
  • Invert flask several times to ensure uniform solution.
27
Q

how do you work out percentage error?

A

maximum error
————————-x100
measurement taken

  • if 2 measurements need to be taken in order to obtain the vlaue, the maximum error must be doubled.
28
Q

how can you reduce error in a titration?

A
  • replace measuring cyclinders with pipettes or burettees.
  • make the titre volume by:
    . increaing volume and concentration of the substance in the conical flask.
    . or decrease concentration of the substance in the burette.