amount of substance Flashcards

1
Q

what is the relative atomic mass?

A

the average mass of an atom or isotope compared to the mass of carbon 12

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2
Q

what is the relative formula/ molecular mass?

A

the mass of a molecule of compared to 1/12 the relative atomic mass of one atom of carbon 12

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3
Q

what is Avogadros constant?

A

1 mole = 6.022x10 23 atoms /particles/molecules of something.

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4
Q

how do you calculate the moles of a substance?

A

moles = mass/mr

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5
Q

how do you figure out the moles of an equation and the number of moles they will make?

A
  1. use the molar ratio given in the question
  2. divide the number of moles you’re given by the number of moles in the question to find the scale factor
  3. times the other moles in the equation b the scale factor to find how many moles would be made
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6
Q

how do you figure out the mass of a reactant or product that will be made?

A
  1. find out the moles of the element of the mass that you know using. mass = Mr x moles
  2. use the molar ratio given in the balanced equation to figure out the moles of the element you’re looking for.
  3. once the moles of the element your looking for have been found use this to find out the mass by using moles = mass/mr rearranged/
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7
Q

how do you figure out the limiting reagent in a question?

A
  1. look at the amount of moles needed for the reactants to react fully
  2. look at the moles of the reactants and decide which is in excess, and which one is limiting
  3. the limiting reagent will have to figure out how many moles will react and how many will be left over you can use this to figure out how many moles will react and how many will be left over.
  4. if you’re given the masses you can figure out the moles by using moles = mass/ mr
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8
Q

how do you measure the mass of the solid used for the volumetric solution?

A
  1. Zero the balance, then place a weighing boat onto the balance and record its mass
  2. add the rough amount of solid to the boat and record the mass
  3. add the solid mass to a beaker and record the mass of the boat again
  4. if you subtract the mass of the weighing boat and solid by the mass of the weighing boat by itself, you should get the mass of the solid. this is called weighing by difference
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9
Q

how do you make a volumetric solution?

A
  • into a small beaker, add 50 cm^ of distilled water and add the solid, stirring until completely dissolved.
  • then transfer the contents of the beaker into a 250 cm^3 volumetric flask, don’t filter it. rinse the beaker and add the washing
  • then slowly add more water using a dropper until the solution reaches the calibration mark at 250 cm^3
  • add the stopper and invert 10 times to mix the solution thoroughly.
  • to find out the concentration do conc. = moles/volume
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10
Q

how do you calculate the uncertainty?

A

uncertainty = error value of equipment/value measured x 100
- you must remember how many times you used the balance, then times the error value by this number

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11
Q

how do you calculate the concentration of a solution?

A

concentration = moles /volume.

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12
Q

how do you convert the volume from cm^3 into m^3?

A

times by 10 -6

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13
Q

how do you calculate the experimental error of an experiment?

A

experimental error = measured value - real value / real value
- if this is greater than the total apparatus uncertainty the the experiment is inaccurate.

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14
Q

how do you perform a tiration?

A
  • use the pipette and pipette filler to add a 25 cm^3 volume of sodium hydroxide solution to a clean conical flask.
  • add a few drops of indicator and put the conical flask on a white tile to see the colour change better
  • fill the burette with HCl and note the starting volume
  • slowly add the acid from the burette to the alkali in the conical flask, swirling constantly to mix
  • stop adding the acid when the endpoint is reached, (when the indicator first changes colour) and not the final volume on the burette
  • calculate the titre by subtracting the starting value on the burette from the end value.
  • repeat the steps above until you get concordant results (results within 0.01 of each other) and do drop by drop near the end.
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15
Q

How do you work out the concentration of an acid/alkali using the results of a titration?

A
  1. write out the equation and balance it.
  2. calculate the number of moles of the element that you know the concentration and volume of. don’t forget to convert the concentration form cm^3 into dm ^3 by dividing by 1000
  3. looking at the molar ratio in the equation find out the moles of the acid/ alkali you are looking for., then to find out the concentration, use the equation concentration = moles /volume.
    9 to find the volume rearrange the equation.
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16
Q

What is the ideal gas equation?

A

p(Pa)V (m^3)= nRT pressure x volume (m^3) = number of moles x gas constant x temperature (k) (dont forgert to convert into standard conditions)

17
Q

when working out the volume of a solution what must you convert it to?

A

cm^3 -> Dm^3 by dividing by 1000

18
Q

what is the empirical formula?

A

the simplest whole number ratio of elements in a compund.

19
Q

how do you calculate the empirical formula?

A
  1. write out the elements involved
  2. write the percentages or masses down
    3, divide the percentages/ masses by the me to get the number of moles
  3. then divide by the smallest one to get the ratios
  4. you can round if the number is close to another
20
Q

how do you calculate the molecular formula ?

A
  1. work out the mr of the empirical formula
  2. divide this number by the mr of the molecular formula
  3. use this number and multiply by all the atoms in the empirical formula to get molecular formula.
21
Q

What is the theoretical yeild?

A

the amount of a product produced assuming no products are lost an all reactants react fully.

22
Q

how do you calculate the theororetical yield?

A
23
Q

how do you calculate the percentage yield?

A

percentage yield = actual yield /theorectical yield x 100

24
Q

why is perecentage yield never 100%?

A
  • not all of the reactants may have reacted
  • ## if product is a gas it may be lost to the environment
25
Q

what is the atom economy?

A

How efficient a reaction is.

26
Q

how do you calculate atom economy?

A

% atom economy = molecular mass of product/sum of molecular masses of all reactants x 100
(remember you may need to write the equation out first and balance it also when finding the mss of desired product you must times by the moles infront of it)

27
Q

Why is atom economy important?

A
  • companies will try to use reactions that tend towards 100% atom economy
  • high atom economies produce less waste and so benefit from the envrionment
  • high atom economies means that raw materials are used more efficiently. this is more sustainable
    -higher atom economy means less by- products so less time spent seperating these from desirable products.