amino acids, amides and chirality Flashcards

1
Q

general formula for an alpha-a.a

A

RCH(NH2)COOH

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2
Q

structure of an alpha-a.a

A

amine group attached to the second carbon next to the carboxyl group

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3
Q

structure of a beta-a.a

A

amine group attached to the third carbon next to the carboxyl group

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4
Q

what are the reactions of the carboxylic acid group in a.as

A

with alkalis- neutralisation

esterification with alcohols

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5
Q

what reactions can the amine group of a.a undergo

A

with acid to form ammonium salts

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6
Q

ionic eq for alpha a.a and HCl

A

.

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7
Q

eq for a.a and alkali

A

.

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8
Q

eq for a.a and XS ethanol in the presence of H2SO4

A

.

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9
Q

what allows a.a to undergo reactions

A

the lone pair on the N accepts H+s

OH an O of c.acid have lone pairs they can donate

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10
Q

functional groups on a.a

A

amine group

carboxylic acid group

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11
Q

how many common a.a do our body have

A

20

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12
Q

what do a.a differ by

A

side chain, R group, variable

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13
Q

zwitterion

A

ion with positive and negative charge

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14
Q

how is a zwitter ion formed

A

amine group on a.a. acc prton from c.acid group

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15
Q

what is the overall charge of a zwitter ion

A

has no overall charge

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16
Q

why don’t zwitter ions have an overall charge

A

the positive charge on the N and negative charge on the O cancel out

17
Q

isoelectric point

A

pH at which the zwitter ion is formed

18
Q

what happens when an a.a is added to a solution with a pH greater than its isoelectric point

A

a.a acts as acid and loses a proton

19
Q

what happens when an a.a is added to a sol w/pH below i.point

A

a.a beh as base and gains a proton

20
Q

what are amides the products of

A

reactions of acyl chlorides w/ammonia and amines