amine Flashcards

1
Q

What is a primary amine

A

NH2 bonded to oe carbon

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2
Q

is ammonia a base or acid

A

base

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3
Q

Amine + acid

A

Salt

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4
Q

How do you make primary aliphatic amines

A

Haloalkanes reacted with excess ammonia in ethanol

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5
Q

What mechanism is making amines

A

nucleophilic substitution

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6
Q

Why is ethanol needed

A

Prevents water from reacting with haloalkane to make alcohol

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7
Q

Why is excess NH3 used

A

prevents further substitution from secondary and tertiary amines

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8
Q

How do you make primary aromatic amine

A

reduce with tin and con H2so4 under reflux to form ammonium salt,then NaOH

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9
Q

What does CH3CH2Nh2 and H2SO4 make

A

(CH3Ch2NH3+)2 SO4 2-

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10
Q

do alcohols or anime have a high bp

A

alcohol - oxygen is more electronegative

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11
Q

Explain why amines can behave as bases

A

Lone pair of N can accept H+ by forming a dative covalent bond

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12
Q

What is a sterioisomer

A

same structural formula different arrangement of atoms

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13
Q

What is an alcohol oxidised

A

Carboxilic acid and wotar

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14
Q

Why is anhydride used insteas of acyl chlorides sometimes

A

Less corrosive

less vunerable to hydrolysis

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15
Q

Why might polyesters with c=o be easier to break down

A

absorbs radiation and breaks down

ester linkage can be hydrolysed

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