Amalgam Flashcards
Dental Amalgam, prior to mixing, consists of a powder of
amalgam alloy and a metallic liquid of elemental mercury.
Dental Amalgam consists of a variety of intermetallic compounds
before and after mixing and final setting.
intermetallic, also called an intermetallic compound, or an intermetallic alloy, or an ordered intermetallic alloy, or a long-range-ordered alloy
is a solid-state compound exhibiting metallic bonding, defined stoichiometry and ordered crystal structure
amalgam alloy powder consists of a metallic phase called
gamma (γ), a silver-tin alloy consisting of the intermetallic compound, Ag3Sn
Various alloy particle types include
Comminuted (lathe-cut or pulverized)
• Spherical
• Blended: comminuted + spherical
Spherical alloy requires less mercury
to adequately titurate.
Spherical alloy easier to
But harder to
Condense
Create contact
Amalgam Alloy Composition Types:
1) LOW COPPER (2-5%);
2) HIGH COPPER (10-30%)
CONVENTIONAL AMALGAM (low copper) reaction is a
solution precipitation process.
GAMMA is
SILVER-TIN phase.
GAMMA-1
SILVER-MERCURY phase.
GAMMA-2
TIN-MERCURY phase.
Gamma-2 is a problem in low copper alloys bc:
1) corrosion-prone;
2) weakest component;
3) connecting blade-like geometry
4) penetrating corrosion
HIGH COPPER AMALGAMS:
- Suppression of gamma-2 phase (Sn-Hg)
- Preferential formation of Sn-Cu
- Immediate or delayed gamma-2 suppression
ELIMINATION OF GAMMA-2 occurs by two distinct mechanisms:
Admixed and unicompositional
Admixed
gamma-2 forms around silver-tin (gamma) particles and is eliminated around silver-copper particles
Unicompositional
Ag-Sn-Cu particles first function like Ag-Sn particles, then they function like Ag-Cu particles, above.
SOURCE OF COPPER - HIGH COPPER AMALGAM:
silver-copper (Cu3Sn) “epsilon” phase
HIGH-COPPER ADVANTAGES
- improved strength
- corrosion resistance
- marginal integrity
- less creep
DISPERSALLOY High copper
- Blended-Admixed-Dispersion
- Traditional lathe cut particles
- Spherical silver-copper eutetic
UNICOMPOSITIONAL “HIGH-COPPER” AMALGAM: Reaction Mechanism:
Ag-Sn-Cu + Hg Gamma-1 + Eta + Ag-Sn-Cu
Alloy particles Mercury Ag-Hg Cu-Sn Alloy particles
TRITURATION
Combining amalgam alloy with mercury by vigorous mixing to form a plastic mass of dental amalgam
CONDENSATION
Adaptation of the plastic dental amalgam mass into the cavity preparation by compressing with pressure
Working time
DECREASED by over-trituration for all types
Contraction
SLIGHTLY INCREASED by over-trituration for all types
Compressive/Tensile strength
INCREASED by over-trituration for lathe-cut MAXIMUM by normal trituration for spherical
Creep
Permanent deformation under load in a set material
INCREASED by over-trituration, DECREASED by under-trituration
Heating
INCREASED by overtrituration, speeding reaction rate
Amalgam displays two types of dimensional change:
1) initial or setting change; 2) delayed or secondary.
BEST MANAGEMENT PRACTICES
- use precapsulated alloys
- recycle used capsules
- salvage contact amalgam / recycle
- use chairside traps / recycle
- recycle vacuum filter contents
- DON’T incinerate extracted teeth with amalgam restorations
- DON’T use bleach in suction lines