Amalgam Flashcards
Dental Amalgam, prior to mixing, consists of a powder of
amalgam alloy and a metallic liquid of elemental mercury.
Dental Amalgam consists of a variety of intermetallic compounds
before and after mixing and final setting.
intermetallic, also called an intermetallic compound, or an intermetallic alloy, or an ordered intermetallic alloy, or a long-range-ordered alloy
is a solid-state compound exhibiting metallic bonding, defined stoichiometry and ordered crystal structure
amalgam alloy powder consists of a metallic phase called
gamma (γ), a silver-tin alloy consisting of the intermetallic compound, Ag3Sn
Various alloy particle types include
Comminuted (lathe-cut or pulverized)
• Spherical
• Blended: comminuted + spherical
Spherical alloy requires less mercury
to adequately titurate.
Spherical alloy easier to
But harder to
Condense
Create contact
Amalgam Alloy Composition Types:
1) LOW COPPER (2-5%);
2) HIGH COPPER (10-30%)
CONVENTIONAL AMALGAM (low copper) reaction is a
solution precipitation process.
GAMMA is
SILVER-TIN phase.
GAMMA-1
SILVER-MERCURY phase.
GAMMA-2
TIN-MERCURY phase.
Gamma-2 is a problem in low copper alloys bc:
1) corrosion-prone;
2) weakest component;
3) connecting blade-like geometry
4) penetrating corrosion
HIGH COPPER AMALGAMS:
- Suppression of gamma-2 phase (Sn-Hg)
- Preferential formation of Sn-Cu
- Immediate or delayed gamma-2 suppression
ELIMINATION OF GAMMA-2 occurs by two distinct mechanisms:
Admixed and unicompositional