ALL OF CONDUCTION TO MEMORISE Flashcards
what is temp?
A measurement of one type of energy that exists in a substance. This can be considered to be the K.E possessed by the atoms and molecules.
If we increase the KE of a noble gas, what happens?
Because noble gases are made up of atoms and not molecules it is safe to assume all KE will be used to increase the velocity of the gas atoms.
If we increase the KE of a non atomic gas (made of molecules) what happens?
It is possible for some of the KE to be absorbed in making the molecules vibrate and rotate, so not all KE translates to velocity. BUT WE CAN OFTEN IGNORE THIS.
How does a liquid behave differently to a gas?
The distance between atoms / molecules is much smaller, it is also less valid to assume elastic interactions between atoms/molecules. (elastic interactions are those which don’t involve loss of KE)
What does increasing temp do to atoms in a solid?
Atoms and molecules are tied in place by bonds here so increased temp causes them to vibrate vigorously around their mean positions. If temp is increased further the vibrations can become so large that the bonds break and the solid melts or decomposes.
What is heat?
The flow of energy that results from temp gradients
What is Fouriers law and what is its other name?
q/A is directly proportional to dt/dx.. the law of heat conduction
Describe conduction on a microscopic scale?
Rapidly moving or vibrating atoms / molecules interact with one another transferring some of their KE.
Why are fluids less conductive than solids?
Because the large distance between atoms means less likely collisions to occur and so less conduction.
Does conductivity increase or decrease with temp?
increase
Draw the pressure vs conductivity graph and describe it?
- Radiation dominates 2. Pressure increasing causes conductivity to increase due to more particles per unit volume so more collisions 3. At a certain point the mean free path is such that the particles are expected to collide with each other before transferring heat from one surface to another.
How is heat transferred by conduction in a solid?
When adjacent atoms vibrate against one another or as electrons move through the the solid between atoms (for conductive solids)
Why is conduction greater in solids?
Because the network of relatively fixed spatial relationships between atoms helps to transfer energy between them by vibration.
What is the zeroth law of thermodynamics?
If two systems are in thermal equilibrium with a third system, they are also in thermal equilibrium with each other.
What is the first law of thermodynamics?
dU = dQ - dW
What is the second law of thermodynamics?
dS>=0
What is the third law of thermodynamics?
s=0 when T=0
What assumptions does the Kinetic Theory of Gases rely on?
- The particles are so small that the overall volume of all the particles added up is negligible compared to the volume of the container.
- These particles all have the same mass.
- The number of particles is large enough for statistical treatment to be applied.
- The particles are in constant rapid and random motion
- The particles constantly collide with themselves and the walls of the container. All of these collisions are perfectly elastic.
- Except during collisions, the interaction between particles is negligible.
- The average KE of the gas particles depends only on the temp of the system.
Eqn describing the KE of a single particle?
0.5mv^2=1.5k_bT