Alkene Reactions Flashcards

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Hydrohalogenation

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2
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Hydrohalogenation (withRearrangement)

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3
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Halogenation

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4
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Hydrobromination with Peroxide

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5
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Hydration

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6
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Hydration (with Rearrangement)

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7
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Bromination in H2O

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8
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Oxymercuration Demercuration

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9
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Hydroboration Oxidation

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10
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Syn-Dihydroxylation

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11
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Syn-Dihydroxylation

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12
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Anti-Dihydroxylation

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13
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Addition of an Alcohol

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14
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Bromination in Alcohol

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15
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Catalytic Hydrogenation

Pt can also be used

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16
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A

An alkene is treated with HBr (in the absence of
peroxides), so we expect a Markovnikov addition of H and Br across the π bond. That is, Br is installed at the more substituted position:

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17
Q
A

An alkene is treated with HBr in the presence of
peroxides, so we expect an anti-Markovnikov addition ofH and Br across the  bond. That is, Br is installed at the
less substituted position

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18
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19
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20
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An alkene is treated with HI, so we expect a
Markovnikov addition of H and I across the  bond. That is, iodine is installed at the more substituted position

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21
Q
A

An alkene is treated with HBr in the presence of
peroxides, so we expect an anti-Markovnikov addition of H and Br across the π bond. That is, Br is installed at the less substituted position

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26
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Compound A has the molecular formula C5H10. Hydro boration-oxidation of compound A produces 2-methylbutan-1-ol. Draw the structure of compound A.

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