Alkene Products, Reactancts? Flashcards
Anti markovnikov OH addition
- BH3
- H2O2, NaOH
Switching Alkene to more stable carbocation
Just acid, H3PO4 or H2SO4
Single halide to more stable part of alkene (more stable carbocation)
HX
Adding an OH to more stable carbocation
Acid and water (H2PO4/H2SO4 & H2O)
Forms 3 membered ring with halide and then both carbons of alkene anti add with halide
X2
OH to more stable carbocation, halide to other, no rearrangements
X2, H2O
Markovnikov OH addition, no rearrangements
- Hg(OAc)2, H2O
- NaBH4
Anti Markovnikov Oh addition
- BH3
- H2O2, NaOH
Adding 2 OH’s to both sides of alkene
- OsO4
- NaHSO3
Removes all alkenes and alkenes pi bonds adding H’s
H2, Pd/C
Alkene forms 3 membered ring with oxygen
MCPBA
Ozonolysis, Hydrogens stay as H
- O3
- Zn, HOAc
Ozonolysis, Hydrogens become OH
- O3
- H2O2, NaOH
Alkyne Markovnikov oh that “fixes” enol
HgSO4, H2SO4, H2O