Alkanes And Structural Isomerism Flashcards

1
Q

What is a sigma bond?

A

Head on overlap of two atomic orbitals directly in line between the two bonded atoms

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2
Q

Structural isomer definition

A

A structural isomer has the same molecular formula but a different structural formula

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3
Q

What reactions do alkanes participate in ?

A

Combustion and radical substitution

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4
Q

What are the steps in the radical substitution mechanism

A
  1. Initiation - formation of the radicals
  2. Propagation - two steps to create the products and regenerate the radical
  3. Termination - three possible combinations of the radicals
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5
Q

Homolytic fission definition

A

The breaking of a covalent bond with one of the bonded electrons going to each electron, forming two radicals

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