alkanes Flashcards
outline how different fractions are obtained in fractional distillation
-crude oil is vaporised
-the vapour passes into the fractioning coloumn
-the top of the coloumn is cooler and the bottom of the coloums are hotter due to a negative temperature gradient
-fractions are separated by boiling points
-longer hydrogencarbons have higher boiling points so stay at the bottom
-shorter hydrocarbon flow to the top as they have lower boiling points
thermal cracking
-conditions are high temp and high pressure
-uses free radical intermediates
-produces a high percentage of alkenes and straight chain alkanes
catalytic cracking
-conditions are low temperature and slight pressure
-uses the catalyst ‘zeolite’
-uses carbocation intermediates
-produces mainly motor fuels and aromatic hydrocarbons and cyclo alkanes
why do we carry out cracking reactions
-shorter chains are in higher demand
-other products such as alkenes are used to make plastics and polymers
how is carbon monoxide formed and what problems does it cause and how to reduce the problem
-its formed from incomplete combustion
-its is very toxic
-you can reduce the problem by using catalytic converters in cars
how is carbon particulates formed and what problems does it cause and how to reduce the problem
–its formed from incomplete combustion
-it can cause respiratory problems
-you can reduce the problem by supplying good amount of oxygen when burning fuels
how is unburnt hydrocarbons formed and what problems does it cause and how to reduce the problem
-its formed when hydrocarbons arent burned at all
-it causes photochemical smog
-it can be reduced by using a catalytic converter in cars
how is NO & NO2 formed and what problems does it cause and how to reduce the problem
-its formed by combustion of N2 gases with O2 in the air at very high temps
-reacts with water to form acid rain
-can be reduced by using a catalytic converter in cars
how is sulfur dioxide formed and what problems does it cause and how to reduce the problem
-formed from combustion of sulfur containing compounds
-reacts with water to form acid rain
-it can be reduced by removing SO2 from