Alkanes Flashcards

1
Q

what are alkanes

A

they are a homologous series of saturated hydrocarbons

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2
Q

what’s alkanes general formula

A

CnH2n+2

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3
Q

are alkanes reactive and why

A

no due to strong covalent bonds between atoms

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4
Q

although alkanes are unreactive what can they do

A

alkanes can burn in oxygen (combustion)

and they can react with halogens to form halogenoalkanes

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5
Q

explain the trend in BP of straight chain alkanes

A

as chain length increases/mr surface area contact increases, more van der waals forces can form between molecules which takes more energy to break

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6
Q

what happens to BP with branched isomers of alkanes

A

BP decreases as the more branched a molecule is, less van der waal forces can form between molecules

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7
Q

are alkanes polar or non polar

why

A

non polar

C-H do not have a large difference in electronegativity

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8
Q

are alkanes soluble in water

A

no

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9
Q

what are alkanes used for

A

fuels and as starting materials (pharmaceuticals)

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10
Q

how is crude oil made

A

it is a fossil fuel and is formed from the remains of plants and animals and over millions of years heat and pressure convert these chemicals into crude oil

it is non renewable

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11
Q

what is in crude oil

A

a complex mixture of mainly alkanes (straight,branched and cycloalkanes),

some aromatic compounds (contains benzene)

and other compounds containing S,O,N

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12
Q

what is most of the crude oil mixture

what is in most demand

A

longer chain alkanes

shorter chain ones like naptha

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13
Q

what is cracking

A

cracking is the breaking of longer chain alkanes into smaller ones

cracking includes breaking the strong C-C covalent bonds

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14
Q

why do we carry out cracking (2(

A

1) shorter chains are higher in demand

2) alkenes are used to make plastic and polymers

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15
Q

are alkenes highly reactive

A

yea

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16
Q

describe thermal cracking

A
  • long chain alkanes cracked with:
  • high temperatures
  • high pressure

*and produces high percentage of alkenes and straight chain alkanes
* hydrogen can also be a product

17
Q

what is an advantage to thermal cracking

A

high percentage of alkenes produced which are very useful molecules due to their high reactivity

18
Q

describe catalytic cracking

A

long chain alkanes cracked

with high temperatures and moderate pressures

uses ZEOLITE catalyst

forms branched chain alkanes (motor fuels) , cycloalkanes and aromatic hydrocarbons

19
Q

what is made in complete combustion of alkanes

A

co2 and water

20
Q

what is made in incomplete combustion of alkanes

A

CO or C

CO is a toxic gas
C is particulate and causes global dimming

21
Q

what are the pollutants from car engines

how can they be removed

A

C
CO
NO2 and NO
unburnt hydrocarbons

by catalytic converters in cars

22
Q

what are the pollutants from coal burning power stations

how can this be removed and with what molecules

A

SO2

by flue gas desulfurisation using CaO or CaCO3 (bases)

23
Q

what happens when nitrogen oxides react with water

A

acid rain forms