ALKANES Flashcards

1
Q

What is an alkane

A

a fully saturated hydrocarbon

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2
Q

What shape are alkanes

A

tetrahedral around each carbon

bonding angles are 109.5

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3
Q

Why are alkanes used as fuels

A

they release large amounts of energy and burn quite readily

alkanes burn in plentiful oxygen completely*

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4
Q

What are alkanes used for in real life

A

used to power vehicles and to generate electricity by combustion

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5
Q

How to work out formula of a hydrocarbon being burnt

A

use the information given to write a volume ratio and deduce from there by balancing the equation

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6
Q

what is produced from incomplete combustion of alkanes

A

Carbon monoxide or Carbon(soot)

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7
Q

What happens in the initiation step of a free radical chain reaction

A

Radicals are produced using visible or UV light by homolytic fission

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8
Q

What happens in the propagation step of a free radical chain reaction

A

A radical can react with a non radical molecule, this creates a new radical which can react with other non radicals, this is called a chain reaction

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9
Q

What happens in the termination step of a free radical chain reaction

A

2 radicals react to form a non radical, this ends the chain reaction

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10
Q

Give the free radical substitution mechanism to make chloromethane

A

I Cl2 –>(UV) Cl. + Cl.

P Cl. + CH4 –> CH3. + HCl
CH3. + Cl2 –> CH3Cl + Cl.

T CH3. + Cl. –> CH3Cl

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11
Q

How can impurities be made in free radical reactions and how can this be reduced

A

An excess of radicals can react with the desired product to undergo further reactions, and the product of this can react even further

can be prevented by adding excess of the non radical molecule of the reaction

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12
Q

How can isomers be formed in free radical substitutions

A

as the radical will react anywhere on the hydrocarbon chain

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