Aliphatic - Organic Chemistry Reactions. Flashcards

Reactions with Reagents, Conditions and Type of Reaction.

1
Q

Alkane to Haloalkane.

A

Halogen (X2).

Conditions: UV light.

Reaction: Radical Substitution.

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2
Q

Alkene to Haloalkane.

A

Hydrogen Halide (HX).

Conditions: ———

Reaction: Electrophilic Addition.

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3
Q

Alcohol to Haloalkane.

A

Sodium Halide (NaX) with H₂SO₄.

Conditions: ———

Reaction: ———

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4
Q

Alkene to Alkane.

A

Hydrogen (H2) with Nickle (Ni) Catalyst.

Conditions: 150°C & 5atm.

Reaction: ———

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5
Q

Alkene to Alcohol.

A

Steam (H2O(g)) with Conc H₃PO₄ Catalyst.

Conditions: 300°C & 60atm.

Reaction: Hydration Addition.

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6
Q

Haloalkane to Alcohol.

A

Aqueous Sodium Hydroxide (NaOH).

Conditions: Under Reflux

Reaction: Nucleophilic Substitution.

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7
Q

Haloalkane to Nitrile.

A

Sodium Cyanide (NaCN)/ Ethanol solution.

Conditions: Under Reflux.

Reaction: Nucleophilic Substitution.

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8
Q

Haloalkane to Amine.

A

Conc. Ammonia (NH3).

Conditions: In an Ethanol Solution.

Reaction: Nucleophilic Substitution [Sₙ2].

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9
Q

Alcohol to Alkene.

A

Conc H₂S0₄ or H₃PO₄.

Conditions: Heat.

Reaction: Dehydration Elimination.

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10
Q

Alcohol to Aldehyde.

A

Primary Alcohol with Acidified (K₂)Cr₂O₇²⁻.

Conditions: Distil.

Reaction: Oxidation.

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11
Q

Alcohol to Ketone.

A

Secondary Alcohol with Acidified (K₂)Cr₂O₇²⁻.

Conditions: Reflux.

Reaction: Oxidation.

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12
Q

Alcohol to Carboxylic Acid.

A

Primary Alcohol with Acidified (K₂)Cr₂O₇²⁻.

Conditions: Reflux.

Reaction: Oxidation.

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13
Q

Aldehyde to Carboxylic Acid.

A

Acidified (K₂)Cr₂O₇²⁻.

Conditions: Reflux.

Reaction: Oxidation.

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14
Q

Aldehyde to Alcohol.

A

NaBH₄ and Water.

Conditions: Heat.

Reaction: Reduction.

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15
Q

Ketone to Alcohol.

A

Water and NaBH₄ in an Alcoholic/Alkali Solution.

Conditions: Heat.

Reaction: Reduction.

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16
Q

Carboxylic Acid to Acyl Chloride.

A

Thiomly Chloride (SOCl₂).

Conditions: Reflux.

Reaction: Substitution.

17
Q

Carboxylic Acid to Ester.

A

Alcohol with Conc. H₂SO₄.

Conditions: ———

Reaction: Esterification.

18
Q

Acid Anhydride to Carboxylic Acid and Ester.

A

Alcohol.

Conditions: Heat.

Reaction: Esterification.

19
Q

Acid Anhydride to Carboxylic Acid and Amide.

A

Ammonia (NH3).

Conditions: Reflux.

Reaction: Acylation.

20
Q

Ester to (Alcohol and) Carboxylic Acid.

A

Dilute Acid.

Conditions: Heat and Reflux.

Reaction: Hydrolysis.

21
Q

Ester to (Alcohol and) Carboxylate ion.

A

Alkali (OH-) and Water.

Conditions: Heat and Reflux.

Reaction: Alkaline Hydrolysis.

22
Q

Acyl Chloride to Carboxylic Acid.

A

Water (H2O).

Conditions: ———

Reaction: Hydrolysis.

23
Q

Acyl Chloride to Ester.

A

Alcohol.

Conditions: ———

Reaction: Acylation.

24
Q

Acyl Chloride to Primary Amide.

A

Ammonia (NH3).

Conditions: ———

Reaction: Acylation.

25
Q

Acyl Chloride to Secondary Amide.

A

Primary Amide.

Conditions: ———

Reaction: Acylation.

26
Q

Nitrile to Amine.

A

Hydrogen (H2) with Nickle (Ni) Catalyst.

Conditions: ———

Reaction: Reduction

27
Q

Ketone to Hydroxynitrile.

A

Sodium Cyanide (NaCN)/ H+(aq).

Conditions: ———

Reaction: Nucleophilic Addition.

28
Q

Hydroxynitrile to Amine.

A

Hydrogen (H2) with Nickle (Ni) Catalyst.

Conditions: ———

Reaction: ———

29
Q

Hydroxynitrile to Carboxyllic Acid.

A

H2O with HCl.

Conditions: Heat.

Reaction: Hydrolysis.

30
Q

Nitrile to Carboxyllic Acid.

A

H2O with HCl.

Conditions: Heat.

Reaction: Hydrolysis.