Aliphatic Organic Flashcards
Acyl chloride > 2 Amide
RNH2, reflux, RTP (Acylation)
Acyl chloride > Ester
1 Alcohol, RTP (Acylation)
Amide > Carboxylic acid
Dilute HCl (Acid hydrolysis)
Acyl chloride > 1 Amide
concentration NH3, RTP (Acylation)
Acyl chloride > Carboxylic acid
Water, RTP (Acylation)
Carboxylic acid > Acyl chloride
SOCl2, RTP
Ester > Carboxylic acid
H+ catalyst, RTP
Carboxylic acid > Ester
1 Alcohol, H+ catalyst, RTP (Esterification)
Ester > 1 Alcohol
H+ catalyst, RTP
1 Alcohol > Ester
Carboxylic acid, H+ catalyst (Esterification)
Carboxylic acid > Aldehyde
LiAlH4, dry ether (Reduction)
Aldehyde > Hydroxynitrile
H2SO4, KCN/HCN, RTP (N.A.)
Aldehyde > Carboxylic acid
K2Cr2O7, H+ catalyst, reflux (oxidation)
1 Alcohol > Aldehyde
K2Cr2O7, H+ catalyst, distillation (oxidation)
Nitrile > Carboxylic acid
H2SO4, reflux (Acid hydrolysis)
Haloalkane > Grignard
Mg, dry ether, reflux
Grignard > Carboxylic acid
CO2
Haloalkane > 1 Amine
conc NH3, ethanol, high pressure (N.S.)
Nitrile > 1 Amine
H2, Pt catalyst (Reduction)
Haloalkane > 1 Alcohol
NaOH (N.S.)
Haloalkane > Nitrile
KCN/HCN, ethanol (N.S.)
1 Alcohol > Alkene
Excess H2SO4, heat (Elimination)
1 Alcohol > Haloalkane
HX, H2SO4 catalyst
Alkene > 1 Alcohol
H3PO4, steam, 300C
Ketone > 2 Alcohol
LiAlH4, dry ether (Reduction)
2 Alcohol > Ketone
K2Cr2O7, H+ catalyst, reflux (oxidation)
Ketone > Hydroxynitrile
H2SO4, KCN/HCN, RTP (N.A.)
Alkylhydrogensulfate > 2 Alcohol
H2O
Haloalkane > 2 Alcohol
NaOH, reflux (N.S.)
Alkene > Haloalkane
HX (E.A.)
Alkene > Alkylhydrogensulfate
H2SO4, RTP
Alkene > Dihaloalkane
X2 (E.A)
Alkene > Diol
KMNO4, H2O
Alkene > Alkane
H2, Ni catalyst, heat
Alkane > Alkene
Cracking, heat
Alkane > Haloalkane
HX, UV (Free radical substitution)
Alkene > Polyalkene
High pressure
Free radical substitution
Initiation:
Cl2 > 2Cl*
Propagation 1:
Cl* + C4H10 > C4H9* + HCl
C4H9* + Cl2 > C4H9Cl + Cl*
Termination:
2Cl* > Cl2
2C4H9* > C8H18
Cl* + C4H9* > C4H9Cl
Haloalkane > Alkene
NaOH
Elimination