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Chemistry > Aliphatic Organic > Flashcards

Aliphatic Organic Flashcards

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1
Q

Acyl chloride > 2 Amide

A

RNH2, reflux, RTP (Acylation)

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2
Q

Acyl chloride > Ester

A

1 Alcohol, RTP (Acylation)

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3
Q

Amide > Carboxylic acid

A

Dilute HCl (Acid hydrolysis)

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4
Q

Acyl chloride > 1 Amide

A

concentration NH3, RTP (Acylation)

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5
Q

Acyl chloride > Carboxylic acid

A

Water, RTP (Acylation)

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6
Q

Carboxylic acid > Acyl chloride

A

SOCl2, RTP

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7
Q

Ester > Carboxylic acid

A

H+ catalyst, RTP

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8
Q

Carboxylic acid > Ester

A

1 Alcohol, H+ catalyst, RTP (Esterification)

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9
Q

Ester > 1 Alcohol

A

H+ catalyst, RTP

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10
Q

1 Alcohol > Ester

A

Carboxylic acid, H+ catalyst (Esterification)

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11
Q

Carboxylic acid > Aldehyde

A

LiAlH4, dry ether (Reduction)

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12
Q

Aldehyde > Hydroxynitrile

A

H2SO4, KCN/HCN, RTP (N.A.)

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13
Q

Aldehyde > Carboxylic acid

A

K2Cr2O7, H+ catalyst, reflux (oxidation)

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14
Q

1 Alcohol > Aldehyde

A

K2Cr2O7, H+ catalyst, distillation (oxidation)

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15
Q

Nitrile > Carboxylic acid

A

H2SO4, reflux (Acid hydrolysis)

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16
Q

Haloalkane > Grignard

A

Mg, dry ether, reflux

17
Q

Grignard > Carboxylic acid

A

CO2

18
Q

Haloalkane > 1 Amine

A

conc NH3, ethanol, high pressure (N.S.)

19
Q

Nitrile > 1 Amine

A

H2, Pt catalyst (Reduction)

20
Q

Haloalkane > 1 Alcohol

A

NaOH (N.S.)

21
Q

Haloalkane > Nitrile

A

KCN/HCN, ethanol (N.S.)

22
Q

1 Alcohol > Alkene

A

Excess H2SO4, heat (Elimination)

23
Q

1 Alcohol > Haloalkane

A

HX, H2SO4 catalyst

24
Q

Alkene > 1 Alcohol

A

H3PO4, steam, 300C

25
Q

Ketone > 2 Alcohol

A

LiAlH4, dry ether (Reduction)

26
Q

2 Alcohol > Ketone

A

K2Cr2O7, H+ catalyst, reflux (oxidation)

27
Q

Ketone > Hydroxynitrile

A

H2SO4, KCN/HCN, RTP (N.A.)

28
Q

Alkylhydrogensulfate > 2 Alcohol

A

H2O

29
Q

Haloalkane > 2 Alcohol

A

NaOH, reflux (N.S.)

30
Q

Alkene > Haloalkane

A

HX (E.A.)

31
Q

Alkene > Alkylhydrogensulfate

A

H2SO4, RTP

32
Q

Alkene > Dihaloalkane

A

X2 (E.A)

33
Q

Alkene > Diol

A

KMNO4, H2O

34
Q

Alkene > Alkane

A

H2, Ni catalyst, heat

35
Q

Alkane > Alkene

A

Cracking, heat

36
Q

Alkane > Haloalkane

A

HX, UV (Free radical substitution)

37
Q

Alkene > Polyalkene

A

High pressure

38
Q

Free radical substitution

A

Initiation:
Cl2 > 2Cl*
Propagation 1:
Cl* + C4H10 > C4H9* + HCl
C4H9* + Cl2 > C4H9Cl + Cl*
Termination:
2Cl* > Cl2
2C4H9* > C8H18
Cl* + C4H9* > C4H9Cl

39
Q

Haloalkane > Alkene

A

NaOH
Elimination

Chemistry (6 decks)

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