Aldehyde and ketone Flashcards
What are Aldehydes
In aldehydes, the carbonyl group has one hydrogen atom attached to it together with either a 2nd
hydrogen atom or a hydrogen group which may be an alkyl group or one containing a benzene ring.
What are Ketones
In ketones, the carbonyl group has 2 hydrocarbon groups attached to it. These can be either the ones containing benzene rings or alkyl groups. Ketone does not have a hydrogen atom attached to
the carbonyl group
Aldehydes and ketones are organic compounds which incorporate
a carbonyl functional group, C=O
If at least one of these substituents is hydrogen, the compound is
an aldehyde
If neither is hydrogen, the compound is
a ketone
Combined with other functional group aldehydes and ketone are widespread in nature. Compounds such as
cinnamaldehyde (cinnamon bark), vanillin (vanilla bean), Citra (lemongrass),, and camphor (camphor trees)
are found chiefly in microorganisms or plants.
Whereas, compounds such as testosterone (male sex hormone), and progesterone (female sex hormone), cortisone (adrenal hormone) have animal and human origin.
The C=C of alkenes has an average bond energy of
146 kcal/mole
Since a C–C σ- bond has a bond energy of
83 kcal/mole
the π-bond energy may be estimated at
63 kcal/mole
is the simplest aldehyde
Formaldehyde
is the smallest ketone
acetone
Uses of Aldehydes
Formaldehyde is a gas. With 40% solution in water, it forms Formalin which
is used in preserving biological specimens.
Formaldehyde is used in embalming, tanning, preparing glues and polymeric products, as germicides, insecticides, and fungicides for plants. It is also used in drug testing and photography.
When reacted with phenol, formaldehyde forms Bakelite, which is used in plastics, coatings, and adhesives.
Acetaldehyde is largely used for the production of acetic acid and pyridine derivatives.
Benzaldehyde is used in perfumes, cosmetic products, and dyes. It is added to provide almond flavour to food products and also used as a bee repellent.