Alcohols Flashcards

1
Q

What is the general formula for alcohols?

A

C(n)H(2n+1)OH

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2
Q

What is the functional group of alcohols?

A

-OH (hydroxyl)

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3
Q

What are 4 smallest alcohols?

A
smalles to largest:
Methanol - CH(3)OH
Ethanol - C(2)H(5)OH
Propanol - C(3)H(7)OH
Butanol - C(4)H(9)OH
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4
Q

How does the formula of the first 4 alcohols increase

A

An extra CH(2) is added with each increase

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5
Q

What happens when alcohols react with an oxidising agent?

A

A carboxylic acid is produced

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6
Q

What happen when alcohols react with sodium?

A

Hydrogen is produced

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7
Q

What happens when alcohols react with water?

A

The alcohols dissolve to give a neutral solution

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8
Q

What happens when alcohols react with air (and heat ofc)

A

Carbon dioxide and water is produced

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9
Q

What is a carboxylic acid?

A

A carboxylic acid is an organic compound that contains a carboxyl group

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10
Q

What is the functional group of carboxylic acids?

A

-(COOH) (carboxyl)

-C=O
I
Oh

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11
Q

What is the general formula for carboxylic acids?

A

C(n)H(2n+1)COOH

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12
Q

Are carboxylic acids strong or weak and how do we know this?

A

They are weak acids because they only partially ionise in water (not all the hydrogen atoms disassociate to form H+ ions)

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13
Q

What happens when carboxylic acids react with carbonates?

A

They produce a SALT + CARBON DIOXIDE + WATER

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14
Q

What happens when carboxylic acids react with water

A

They dissolve to give acidic solutions

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15
Q

What happens when carboxylic acids react with alcohols?

A

They produce an ester and water:

E.g. ethanoic acid + ethanol → ethyl ethanoate + water

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16
Q

What is produced when an alcohol is oxidised?

A

The carboxylic acid of that alcohol is produced (e.g when propanol is oxidised, propanoic acid is produced)

17
Q

What is fermentation?

A

The process of adding yeast to a sugar solution, this produces:

  • An aqueous solution of ethanol
  • Carbon dioxide
18
Q

What conditions are necessary for fermentation?

A

ideal conditions are:

  • Temperature at around 37 degrees Celsius
  • A slightly acidic solution
  • Anaerobic condition (no oxygen)
19
Q

How can we extract the ethanol from the ethanol mixture we get from fermentation?

A

We can use fractional distillation to get the ethanol, this allows the producer to make a higher concentration of ethanol

20
Q

What is the general formula for carboxylic acids?

A

C(n-1)H(2n+1)COOH

21
Q

How do we know that alcohol react in a similar way to other alcohols

A

They are members of a homologous series and have the same functional group so we can predict how other molecules in that series will react

22
Q

What will we get when ethanolic acid is dissolved in water

A

Ethanolic acid is slightly ionising so it produces the ethanoate ion and H+