Alcohols Flashcards
How does classification of alcohols work?
Primary - The OH group is on a carbon with one alkyl group
Secondary - The OH group is on a carbon with two alkyl groups
Tertiary - The OH group is on a carbon with three alkyl groups
Combustion of alcohols (equation and details)
- Alcohols burn in excess oxygen to product CO₂ and H₂O
- Burn readily with a light blue flame
CH₃OH(l) + 1.5O₂ –> CO₂ + H₂O
Chlorination of alcohols (producing chloroalkanes)
Alcohols can be chlorinated by HCl or PCl₅
Using PCl₅:
ROH + PCl₅ –> RCl + HCl + POCl₃
Using HCl:
ROH + HCl –> RCl + H₂O
(Tertiary alcohols react the fastest with HCl)
Bromination of alcohols (producing bromoalkanes)
- An inital reaction needs to take place for HBr to be produced
Initial reaction: KBr + H₂SO₄ –> HBr + KHSO₄
(A 50% conc sulfuric acid is used)
Bromination reaction: HBr + ROH –> RBr + H₂O
Iodination of alcohols (producing iodoalkanes)
- Phosphorus triodide (PI₃) is used, produced in situ
How PI₃ is made: 2P + 3I₂ –> 2PI₃
Iodination reaction: SP + 3I₂ –> 2PI₃
Dehydration of alcohols/forming alkenes by elimination (eliminating water)
- Uses an acid catalyst (either H₂SO₄ or phosphoric acid, H₃PO₄)
Alcohol –> alkene + H₂O
ex. C₂H₅OH –> C₂H₄ + H₂O
How many different alkenes are produced by the dehydration of non-primary alcohols?
Non primary alcohols can produce 3 different alkenes
The double bond (made when the alkene forms) can form either side of the carbon that had the OH group
E/Z isomerism forms two different versions of the same positioned alkene